{"id":"W2953147968","doi":"10.1002/chin.201133103","title":"ChemInform Abstract: Strain‐Promoted 1,3‐Dipolar Cycloadditions of Diazo Compounds with Cyclooctynes.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Chemistry; Diazo; Cycloaddition; Strain (injury); Medicinal chemistry; Stereochemistry; Computational chemistry; Organic chemistry; Combinatorial chemistry; Photochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001070426,0.0004470344,0.0004681531,0.0001242895,0.0001364959,0.00003400873,0.0004937247,0.0003265096,0.01814233],"category_scores_gemma":[0.0000498198,0.0004058482,0.0001975671,0.0002878161,0.000265312,0.0005112766,0.00009982457,0.0004788713,0.000131837],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001638515,"about_ca_system_score_gemma":0.000190449,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008926034,"about_ca_topic_score_gemma":0.00006597828,"domain_scores_codex":[0.9978224,6.873145e-8,0.0007113288,0.0003619035,0.0005445275,0.0005597519],"domain_scores_gemma":[0.9979639,0.00005574459,0.0005567856,0.0008460899,0.0002903349,0.0002871639],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003034833,0.0006115774,0.0001954797,0.001605617,0.0003928365,0.00005642576,0.007971095,3.222155e-7,0.5504735,0.001163701,0.003853663,0.4333723],"study_design_scores_gemma":[0.001022674,0.00005957393,0.0008780751,0.0001924359,0.00009794491,0.0001341493,0.002489148,0.000002390325,0.9561659,0.0001835586,0.03826934,0.0005048291],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.04409219,0.0000611338,0.000002153821,0.00001374859,0.00007016054,0.0001719701,0.0005574778,0.0003016077,0.9547296],"genre_scores_gemma":[0.9850256,0.00005668283,0.0006129378,0.0000368703,0.0001446603,0.00008939959,0.001246637,0.00008210071,0.01270512],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.9420244,"threshold_uncertainty_score":0.9998394,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02021195689076884,"score_gpt":0.2157337397431016,"score_spread":0.1955217828523328,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}