{"id":"W2953149037","doi":"10.1002/chin.200438139","title":"Formal Radical Cyclization onto Benzene Rings: A General Method and Its Use in the Synthesis of ent‐Nocardione A.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Advanced Synthetic Organic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Benzene; Radical cyclization; Formal synthesis; Combinatorial chemistry; Medicinal chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003178347,0.0004403252,0.0001763067,0.000418229,0.0003725949,0.0001955486,0.00046226,0.0002538062,0.00381461],"category_scores_gemma":[0.0003195157,0.000143446,0.0002994516,0.000262525,0.0003648456,0.0003451772,0.0005662693,0.0005917797,0.000799792],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002884186,"about_ca_system_score_gemma":0.000500354,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007590457,"about_ca_topic_score_gemma":0.001004137,"domain_scores_codex":[0.9998577,0.00003468258,0.0000107492,0.00003239858,0.0000215882,0.00004294825],"domain_scores_gemma":[0.9999288,0.00001596732,0.00001169836,0.00002107128,0.000007888484,0.00001462945],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000360782,0.0002508795,0.0003042292,0.0007387329,0.0001004958,0.001279584,0.0004409697,0.002995443,0.8805633,0.0164005,0.00245878,0.09410635],"study_design_scores_gemma":[0.0002694336,0.002912143,0.001801942,0.00008841261,0.0001135274,0.002375869,0.0001041396,0.003171833,0.9088553,0.00520929,0.07497959,0.0001185115],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7250333,0.009911986,0.1899902,0.001055954,0.001078409,0.0008917797,0.001334046,0.0009645114,0.0697398],"genre_scores_gemma":[0.9529182,0.005199705,0.03022372,0.0001349246,0.00005831819,0.0002278773,0.0004761336,0.00005943043,0.01070177],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00381461,"threshold_uncertainty_score":0.01276112,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01268815063574028,"score_gpt":0.2525265406963241,"score_spread":0.2398383900605838,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}