{"id":"W2953187037","doi":"10.1002/chin.201416225","title":"ChemInform Abstract: A General Approach to 1‐Hydroxymethylquinolizidine and 8‐Hydroxymethylindolizidine Stereoisomers: Synthesis of (+)‐Epitashiromine (I) and Formal Syntheses of (+)‐Epilupinine (II) and (+)‐Tashiromine (III).","year":2014,"lang":"en","type":"article","venue":"ChemInform","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":false,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Citation; Chemistry; Library science; Chin; Information retrieval; Stereochemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001889613,0.0008929137,0.0002192954,0.0007050836,0.0004143949,0.0004590511,0.0008524278,0.0004105449,0.03951814],"category_scores_gemma":[0.0001396985,0.0002950432,0.0002269771,0.0006237651,0.0002556101,0.0005434699,0.0005893037,0.001029558,0.01486846],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007263788,"about_ca_system_score_gemma":0.00108055,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001246716,"about_ca_topic_score_gemma":0.00251973,"domain_scores_codex":[0.9998715,0.00001398538,0.000006221248,0.00003247067,0.00004831024,0.00002756948],"domain_scores_gemma":[0.9999632,0.000004146285,0.000006146658,0.000006815719,0.00001072993,0.000008994904],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000596113,0.0002763313,0.0002765125,0.001673299,0.00007289575,0.0006785459,0.0002811085,0.001725908,0.6300859,0.08732963,0.05742276,0.2195811],"study_design_scores_gemma":[0.0001501803,0.0003222851,0.0005320277,0.00007123544,0.00003262476,0.0007401739,0.00003017582,0.001251297,0.5503705,0.003700825,0.442755,0.00004372863],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.08696765,0.01342287,0.2648415,0.002671347,0.001416858,0.001260964,0.01594153,0.01037961,0.6030977],"genre_scores_gemma":[0.6031007,0.02773483,0.1385766,0.002044116,0.0006136883,0.001209362,0.01819232,0.001456396,0.2070719],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.03951814,"threshold_uncertainty_score":0.1322014,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01728675680210072,"score_gpt":0.2245737846004862,"score_spread":0.2072870277983855,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}