{"id":"W2953245210","doi":"10.1139/v03-193","title":"Diversity-oriented synthesis of enantiopure <i>N</i>-protected β,β-dialkylserines","year":2004,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Enantiopure drug; Sodium chlorite; Sodium hypochlorite; Metathesis; Reagent; Alcohol; Ring-closing metathesis; Sodium; Salt metathesis reaction; Serine; Organic chemistry; Stereochemistry; Enantioselective synthesis; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002130705,0.0004500883,0.0003262833,0.0002076319,0.0001307785,0.0002657588,0.0003675608,0.00023396,0.001330691],"category_scores_gemma":[0.00018276,0.0001946162,0.0002567045,0.0001691822,0.0001533605,0.000278872,0.0001911967,0.0004932428,0.0005674796],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002793156,"about_ca_system_score_gemma":0.0002187074,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002197922,"about_ca_topic_score_gemma":0.0005857409,"domain_scores_codex":[0.999894,0.00001585917,0.00001418519,0.00002823565,0.00001908553,0.00002857933],"domain_scores_gemma":[0.9999059,0.00001176361,0.00003014742,0.00001357675,0.00001463702,0.00002383934],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008044156,0.00002365645,0.00009868603,0.00007043759,0.00001116959,0.0001307389,0.00004152886,0.0003400921,0.9951158,0.0004649293,0.00007278442,0.003549707],"study_design_scores_gemma":[0.00002619109,0.0003183813,0.0005041213,0.000004772674,0.00001907868,0.0003411771,0.00001388464,0.0003546067,0.9944173,0.0001033448,0.003888842,0.000008243358],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9664665,0.002124894,0.01629529,0.0001163169,0.00009804434,0.0001598325,0.000743854,0.0002300609,0.0137653],"genre_scores_gemma":[0.9790137,0.002285173,0.01325145,0.00007704354,0.00001810109,0.00006285711,0.0005191584,0.00005601638,0.00471649],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001330691,"threshold_uncertainty_score":0.004451632,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009741634628028987,"score_gpt":0.2091498871170496,"score_spread":0.1994082524890206,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}