{"id":"W2953249106","doi":"10.1002/chin.201531218","title":"ChemInform Abstract: Synthesis of Pyrido[2,1‐b]quinazolin‐11‐ones and Dipyrido[1,2‐a:2′,3′‐d]pyrimidin‐5‐ones by Pd/DIBPP‐Catalyzed Dearomatizing Carbonylation.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Quinazolinone synthesis and applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Carbonylation; Catalysis; Combinatorial chemistry; Medicinal chemistry; Stereochemistry; Organic chemistry; Carbon monoxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000432217,0.000746168,0.0003928969,0.0008421743,0.0003779772,0.0006325301,0.0007754941,0.0006314652,0.07032536],"category_scores_gemma":[0.0003326249,0.000319375,0.0004066754,0.001121546,0.0001432215,0.0008439224,0.0005108392,0.0008554205,0.02651261],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009451497,"about_ca_system_score_gemma":0.00128609,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00108013,"about_ca_topic_score_gemma":0.002630194,"domain_scores_codex":[0.9998049,0.00001722762,0.00001320081,0.00003996224,0.0000973529,0.00002734354],"domain_scores_gemma":[0.9998906,0.00001261037,0.00001461763,0.00001190659,0.00004392313,0.00002632244],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000941226,0.0003515026,0.0005316434,0.007171989,0.00020252,0.0007497306,0.000180603,0.001703598,0.3959824,0.01571492,0.2800298,0.2964402],"study_design_scores_gemma":[0.0002826358,0.0005717875,0.00132461,0.0002309832,0.0001146477,0.0004831262,0.00004806613,0.0007559048,0.2670389,0.001807646,0.7272882,0.00005358433],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.08103677,0.1336663,0.02933664,0.00773707,0.004152127,0.001642799,0.0341324,0.002280011,0.7060159],"genre_scores_gemma":[0.2993913,0.126283,0.02073046,0.003304139,0.0006797156,0.0007469573,0.04120398,0.0006344315,0.507026],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.07032536,"threshold_uncertainty_score":0.2352617,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01947658932432065,"score_gpt":0.2386144767537639,"score_spread":0.2191378874294432,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}