{"id":"W2953256875","doi":"10.1021/ol8018709","title":"Highly Regioselective Intermolecular Arylation of 1,2,3,4-Tetrahydropyridines","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Montréal","keywords":"Regioselectivity; Chemistry; Intermolecular force; Computational chemistry; Combinatorial chemistry; Stereochemistry; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00003828594,0.0001403383,0.0001755981,0.00007401185,0.00009914231,0.00001185721,0.0001679651,0.00007268629,0.0003180389],"category_scores_gemma":[0.0001162735,0.0001504958,0.00009863736,0.0002472157,0.0001730734,0.0001053629,0.00003857403,0.0001727928,0.00005794693],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001686417,"about_ca_system_score_gemma":0.0000543061,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008970888,"about_ca_topic_score_gemma":0.000007035693,"domain_scores_codex":[0.9991255,9.292363e-7,0.0002364142,0.0002530927,0.0001990209,0.0001850334],"domain_scores_gemma":[0.9993026,0.00006874053,0.0001431732,0.0003743362,0.00006360018,0.0000475556],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001493275,0.00004639471,0.001804275,0.00002598117,0.00005444965,0.00003770355,0.000447151,0.00002220774,0.9955698,0.00002525512,0.001892313,0.00005949149],"study_design_scores_gemma":[0.0003257436,0.000009525316,0.001312807,0.00002810524,0.00003152559,0.0001882043,0.00003939194,0.0001849587,0.9974486,0.00002340498,0.0002603296,0.0001473914],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979424,0.00003728789,0.0005745796,0.0008498984,0.0001138744,0.00004218733,0.000007011673,0.0001130301,0.0003196812],"genre_scores_gemma":[0.9993855,0.00001498069,0.00004552358,0.0001645874,0.0001341631,0.000004644365,0.00003620344,0.00003852049,0.0001759032],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001878769,"threshold_uncertainty_score":0.6137043,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009379875834189874,"score_gpt":0.2178805132632661,"score_spread":0.2085006374290763,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}