{"id":"W2953264045","doi":"10.1002/chin.200702138","title":"New Methodology Toward Chiral, Non‐Racemic 2,5‐cis‐Substituted Piperidines via Suzuki Cross‐Coupling.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Combinatorial chemistry; Coupling (piping); Suzuki reaction; Enantioselective synthesis; Organic chemistry; Stereochemistry; Catalysis; Palladium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004743276,0.000440515,0.0005255601,0.0001278975,0.0001726811,0.0001234944,0.0004878594,0.0004631126,0.008929451],"category_scores_gemma":[0.0006078769,0.0004525004,0.0002617366,0.0004616998,0.0001948414,0.0003531342,0.0001896653,0.0003563621,0.0002856176],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002811744,"about_ca_system_score_gemma":0.0003423748,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004189094,"about_ca_topic_score_gemma":0.0000212027,"domain_scores_codex":[0.9976147,7.032e-7,0.0008318489,0.0005543871,0.0004135685,0.0005847583],"domain_scores_gemma":[0.9980358,0.0004250165,0.0003459543,0.000721929,0.0002474824,0.0002238035],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004703527,0.0001266704,0.0027504,0.0006046378,0.0001698406,0.00002743002,0.0005376991,0.001317325,0.8349172,0.001898433,0.1017453,0.0554347],"study_design_scores_gemma":[0.001283052,0.00001071176,0.0004934322,0.0000347169,0.00007355118,0.0001385904,0.00006172239,0.002035742,0.897324,0.001618886,0.09639658,0.0005290754],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.1591373,0.001463061,0.137705,0.0007419411,0.002875552,0.0004972416,0.0001186223,0.001532273,0.695929],"genre_scores_gemma":[0.3069183,0.0001375888,0.08757288,0.0006849391,0.008159459,0.0002010178,0.004437323,0.0003272689,0.5915613],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.1477809,"threshold_uncertainty_score":0.9997927,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05012393396898832,"score_gpt":0.326838497531768,"score_spread":0.2767145635627796,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}