{"id":"W2953271295","doi":"10.1002/chin.200249182","title":"ChemInform Abstract: First Syntheses of Two Quinoline Alkaloids from the Medicinal Herb Ruta chalepensis via Cyclization of an o‐Iodoaniline with an Acetylenic Sulfone.","year":2002,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Biological Evaluation","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Quinoline; Chemistry; Sulfone; Herb; Medicinal herbs; Traditional medicine; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000148451,0.0006633211,0.0002917887,0.0005565894,0.0003428084,0.0002750042,0.000516467,0.0002729375,0.00899231],"category_scores_gemma":[0.0001627755,0.0001695285,0.0004131597,0.0003677257,0.0002830626,0.0004405187,0.0003068282,0.0004264982,0.003046062],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002689222,"about_ca_system_score_gemma":0.0007081692,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007642636,"about_ca_topic_score_gemma":0.001575795,"domain_scores_codex":[0.9999124,0.00001339888,0.000009064767,0.00001610233,0.00002237255,0.00002660223],"domain_scores_gemma":[0.9999291,0.00000888918,0.00001629508,0.00001152741,0.00001451122,0.0000195979],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007901348,0.0003603817,0.0004286999,0.002024395,0.0001021606,0.001581716,0.0003875693,0.001379626,0.8845797,0.005342749,0.00719652,0.09582634],"study_design_scores_gemma":[0.0004030297,0.004155186,0.003444226,0.0001095778,0.0001450961,0.001631141,0.0001101312,0.000897476,0.9124196,0.001386333,0.07521781,0.00008036454],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7530251,0.0247211,0.04504176,0.001597277,0.001425956,0.002066948,0.01125586,0.001542276,0.1593237],"genre_scores_gemma":[0.9380848,0.01380499,0.01424196,0.000352702,0.0002437224,0.0002632565,0.00356905,0.0001613379,0.02927818],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00899231,"threshold_uncertainty_score":0.03008229,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04171952076647443,"score_gpt":0.2594482467531121,"score_spread":0.2177287259866376,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}