{"id":"W2953284995","doi":"10.1002/chin.201034093","title":"ChemInform Abstract: Palladium‐Catalyzed ortho‐Arylation of O‐Phenylcarbamates with Simple Arenes and Sodium Persulfate.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Palladium; Catalysis; Electrophile; Reductive elimination; Metalation; Catalytic cycle; Medicinal chemistry; Persulfate; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002467977,0.0002977021,0.0003386583,0.00008653836,0.000104349,0.00006701487,0.0002063461,0.0002568371,0.005796636],"category_scores_gemma":[0.0003016918,0.0002621435,0.0000849881,0.0002123154,0.0002573565,0.0004110085,0.00009696586,0.0002742093,0.00001421465],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004709232,"about_ca_system_score_gemma":0.0001592333,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001021935,"about_ca_topic_score_gemma":0.00007148923,"domain_scores_codex":[0.9984605,6.648996e-8,0.0005466423,0.0003008064,0.0003915089,0.0003004943],"domain_scores_gemma":[0.9983886,0.000220553,0.0004105462,0.0005167253,0.0002858592,0.0001776689],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003874356,0.0001130706,0.01246998,0.001444416,0.000185434,0.000004697555,0.001790716,0.000004012254,0.7660221,0.001097249,0.002254773,0.2142261],"study_design_scores_gemma":[0.001120941,0.00001246504,0.004901569,0.000045658,0.00007052913,0.00005764134,0.0007669476,0.00008890466,0.9683855,0.0001875644,0.02400494,0.0003573184],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5250201,0.00005496908,0.000006233287,0.00006007273,0.00007330129,0.0001082366,0.00006590343,0.0001168935,0.4744943],"genre_scores_gemma":[0.986632,0.00002966595,0.0006769065,0.00003593426,0.0001848424,0.00003764824,0.001309064,0.00004553309,0.01104841],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4634459,"threshold_uncertainty_score":0.9999831,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01368690935592879,"score_gpt":0.2507775636033613,"score_spread":0.2370906542474326,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}