{"id":"W2953291744","doi":"10.1021/ol050014f","title":"A Room-Temperature Protocol for the Rhodium(I)-Catalyzed Addition of Arylboron Compounds to Sulfinimines","year":2005,"lang":"en","type":"article","venue":"Organic Letters","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":96,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Rhodium; Phosphine; Catalysis; Adduct; Combinatorial chemistry; Organic chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004620765,0.0009548917,0.0006012704,0.0005346732,0.0005609812,0.0003192416,0.001517954,0.0005254619,0.003684111],"category_scores_gemma":[0.000231416,0.00055377,0.0004251566,0.0003402621,0.0003432072,0.00045103,0.0005230735,0.001219531,0.002157717],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005990717,"about_ca_system_score_gemma":0.0007373907,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006020046,"about_ca_topic_score_gemma":0.001550772,"domain_scores_codex":[0.9996312,0.00007130665,0.00004931694,0.00007608897,0.00008508033,0.00008705526],"domain_scores_gemma":[0.9998749,0.00001897918,0.00002253713,0.00003320572,0.00001848614,0.00003180313],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001592913,0.0001779459,0.00007628173,0.0004326442,0.00003451481,0.0004161633,0.0001754989,0.0007158114,0.9810644,0.00281129,0.001655545,0.01228057],"study_design_scores_gemma":[0.00009803456,0.000539596,0.000554413,0.00002750267,0.0000333054,0.0006719907,0.00003305631,0.0007054011,0.9755121,0.0005577535,0.02120781,0.00005903646],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.6091044,0.01017832,0.318735,0.001536045,0.0008001078,0.003882066,0.004594445,0.004732765,0.04643685],"genre_scores_gemma":[0.8920789,0.007376032,0.07626988,0.0003464617,0.0001233891,0.002102373,0.003705992,0.0002982932,0.01769873],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.003684111,"threshold_uncertainty_score":0.01232457,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01193390430235354,"score_gpt":0.2565235447913777,"score_spread":0.2445896404890242,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}