{"id":"W2953321229","doi":"10.1021/jo4024039","title":"Dhilirolides E–N, Meroterpenoids Produced in Culture by the Fungus <i>Penicillium purpurogenum</i> Collected in Sri Lanka: Structure Elucidation, Stable Isotope Feeding Studies, and Insecticidal Activity","year":2014,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Trichoplusia; Chemistry; Fungus; Stereochemistry; Sri lanka; Penicillium; Botany; PEST analysis; Food science; Biology; Noctuidae","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000894902,0.000366075,0.0001478541,0.0002994439,0.0001610492,0.0002496513,0.0001494184,0.0001433148,0.0006390185],"category_scores_gemma":[0.000119808,0.0001173506,0.0001742952,0.0003007359,0.0001676563,0.0001701013,0.0001609304,0.0003194934,0.0002431216],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002094597,"about_ca_system_score_gemma":0.0002191395,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001248654,"about_ca_topic_score_gemma":0.002662905,"domain_scores_codex":[0.9999287,0.00000975481,0.000007400946,0.00001989926,0.0000170899,0.00001715545],"domain_scores_gemma":[0.9999125,0.00001608689,0.00002207406,0.00001519849,0.00001543609,0.0000187764],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005019702,0.00001101013,0.0006763359,0.00002207615,0.000003599367,0.00007387384,0.00001915041,0.00005022426,0.997601,0.00001032578,0.000007594107,0.001474649],"study_design_scores_gemma":[0.00001420516,0.0005472063,0.02197612,0.000007933688,0.00002407293,0.0004498649,0.00009666086,0.0001411653,0.9750954,0.00001838896,0.00162202,0.000007013598],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975489,0.0005501359,0.0004324728,0.00001507947,0.000002619917,0.00002141133,0.0005256524,0.00001362974,0.000890132],"genre_scores_gemma":[0.9947584,0.000714811,0.001589424,0.00002151619,0.000005492966,0.00002288474,0.001926968,0.000007813619,0.0009527633],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001248654,"threshold_uncertainty_score":0.002482772,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008122491296659179,"score_gpt":0.2304652898731077,"score_spread":0.2223427985764485,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}