{"id":"W2953351291","doi":"10.1002/chin.201017183","title":"ChemInform Abstract: Palladium‐Catalyzed Intramolecular Carboesterification of Olefins.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Intramolecular force; Palladium; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001309352,0.0002582366,0.0002934661,0.00007793825,0.00006024682,0.00004219773,0.0004385802,0.0003348224,0.003580726],"category_scores_gemma":[0.0002407717,0.0002670693,0.0001812041,0.0001876583,0.000209921,0.0002850163,0.00008855351,0.0004988529,0.0001352074],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001029302,"about_ca_system_score_gemma":0.0001825772,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001149032,"about_ca_topic_score_gemma":0.00003490003,"domain_scores_codex":[0.9984376,1.448936e-8,0.0006189753,0.0002593507,0.0003418328,0.0003421777],"domain_scores_gemma":[0.9981694,0.00006619984,0.0003873896,0.001017066,0.0001716655,0.0001883222],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001705883,0.00006839142,0.00005076195,0.0002178473,0.00004570492,0.0000025446,0.0003065683,7.838133e-8,0.8548278,0.0004026621,0.001133286,0.1429273],"study_design_scores_gemma":[0.0004360281,0.000003658776,0.0006636386,0.00003245254,0.00004884198,0.00005538506,0.0002278957,0.00001291758,0.9414304,0.00006862774,0.0567558,0.0002643057],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3013095,0.00002360711,4.824523e-7,0.00005291207,0.0001228318,0.00007396931,0.00003809845,0.0001037335,0.6982749],"genre_scores_gemma":[0.9900881,0.00002285362,0.00007169491,0.00002476469,0.0001837698,0.00004633621,0.0005706981,0.00003781962,0.008953962],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6893209,"threshold_uncertainty_score":0.9999781,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009207950627877914,"score_gpt":0.2304287089085879,"score_spread":0.2212207582807099,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}