{"id":"W2954236777","doi":"10.1039/c9cc04191e","title":"An earth-abundant system for light-driven CO<sub>2</sub> reduction to CO using a pyridinophane iron catalyst","year":2019,"lang":"en","type":"article","venue":"Chemical Communications","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Fonds de recherche du Québec – Nature et technologies; Japan Society for the Promotion of Science","keywords":"Catalysis; Selectivity; Copper; Chemistry; Photocatalysis; Photosensitizer; Visible spectrum; Photochemistry; Redox; Inorganic chemistry; Materials science; Optoelectronics; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009057565,0.0002722914,0.0002189927,0.0001430626,0.0002591533,0.0002941063,0.0003643677,0.0003356118,0.0007675739],"category_scores_gemma":[0.0001118301,0.00009234325,0.0001028014,0.0001048875,0.0002339618,0.0002946125,0.0002793371,0.0004428074,0.0002803513],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002706404,"about_ca_system_score_gemma":0.0001635013,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006664059,"about_ca_topic_score_gemma":0.001150638,"domain_scores_codex":[0.9998935,0.00001260461,0.000005545649,0.00003362518,0.00003335135,0.00002121142],"domain_scores_gemma":[0.9999492,0.000008367194,0.00000995038,0.000009346536,0.000008634132,0.00001453427],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005052657,0.00003031651,0.000101249,0.00008591687,0.000006201272,0.00007623466,0.00002513924,0.000102621,0.9945902,0.0002814746,0.0001303932,0.004519824],"study_design_scores_gemma":[0.00000941039,0.000141618,0.0004362479,0.000002737188,0.00001073747,0.0001366735,0.00001055028,0.001094504,0.9952127,0.00003653411,0.002902054,0.000006226411],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9736843,0.003207798,0.01778771,0.0001553114,0.00009221997,0.00005513884,0.0001673044,0.0004382997,0.004412046],"genre_scores_gemma":[0.9916126,0.0004089104,0.006363148,0.00002473573,0.00001580117,0.000009366008,0.00012018,0.00002146255,0.001423859],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007675739,"threshold_uncertainty_score":0.002567828,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02733243302119966,"score_gpt":0.2972191911768265,"score_spread":0.2698867581556268,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}