{"id":"W2954944661","doi":"10.1021/acs.jpca.9b04883","title":"Trifluoroacetic Acid and Trifluoroacetic Anhydride Radical Cations Dissociate near the Ionization Limit","year":2019,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Chemical Thermodynamics and Molecular Structure","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Trifluoroacetic anhydride; Trifluoroacetic acid; Chemistry; Ionization; Limit (mathematics); Photochemistry; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002362072,0.0003622316,0.0001881162,0.0002163451,0.000224976,0.0002553772,0.0004132757,0.0002547517,0.002750012],"category_scores_gemma":[0.0003747898,0.0001782331,0.0001522987,0.0001400073,0.0002554871,0.000345467,0.0001390606,0.0003284386,0.0005236327],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003465148,"about_ca_system_score_gemma":0.0001784352,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009237006,"about_ca_topic_score_gemma":0.001327175,"domain_scores_codex":[0.9997976,0.00001162034,0.000008317898,0.00003692138,0.00008629436,0.00005918121],"domain_scores_gemma":[0.9998766,0.00002989351,0.00003263988,0.00001266297,0.00003494399,0.00001322876],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001206907,0.000009180226,0.0004879224,0.00004745141,0.000007598114,0.00005396748,0.00002645531,0.0004235769,0.9957449,0.0006186467,0.0001350665,0.002324598],"study_design_scores_gemma":[0.00002015414,0.0001702232,0.003243021,0.000004245935,0.000007212715,0.0001622531,0.00002997721,0.004041355,0.9896422,0.0002401352,0.00243178,0.000007450832],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9853733,0.0004909151,0.009654987,0.00006113188,0.00001626173,0.0000318632,0.0003113755,0.0001342802,0.003925907],"genre_scores_gemma":[0.9924679,0.0002616563,0.004117055,0.0000389977,0.000004469835,0.00003951056,0.0005510764,0.00002236581,0.002496951],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002750012,"threshold_uncertainty_score":0.009199679,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003954068540359676,"score_gpt":0.2079612731234029,"score_spread":0.2040072045830433,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}