{"id":"W2956747216","doi":"10.1002/anie.201906600","title":"Stabilization of [WF<sub>5</sub>]<sup>+</sup> by Bidentate N‐Donor Ligands","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Dication; Denticity; Raman spectroscopy; Fluoride; Crystallography; Spectroscopy; Nuclear magnetic resonance spectroscopy; Natural bond orbital; Transition metal; Ion; Metal; Inorganic chemistry; Medicinal chemistry; Density functional theory; Stereochemistry; Catalysis; Crystal structure; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001179074,0.0002062439,0.0002113319,0.00009284096,0.00005292022,0.00005349608,0.0002905418,0.0002321238,0.002060127],"category_scores_gemma":[0.00005536703,0.000205611,0.0001370881,0.000157255,0.0000594863,0.0003569312,0.00007770129,0.0002391805,0.0001519965],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000228454,"about_ca_system_score_gemma":0.00005622717,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003625042,"about_ca_topic_score_gemma":0.000002090206,"domain_scores_codex":[0.998455,0.000006405953,0.0004611279,0.0003438392,0.0005154521,0.0002181705],"domain_scores_gemma":[0.9990121,0.00007812453,0.0002629169,0.0002519069,0.000322741,0.00007216961],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007100124,0.000123489,0.001704641,0.00009051862,0.0001338778,0.000002745629,0.000227138,0.0002596518,0.9784781,0.0001946681,0.01826937,0.0004448035],"study_design_scores_gemma":[0.001008212,0.00003573755,0.00006373283,0.000147627,0.00003831654,0.00001699595,0.0002081837,0.001658606,0.9877797,0.0004476457,0.008371935,0.0002232971],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9838561,0.0001427833,0.0004202569,0.000325169,0.0008920666,0.00008648381,0.0002336167,0.00009124888,0.01395231],"genre_scores_gemma":[0.9948456,0.000378927,0.00002809634,0.0001138728,0.0007926043,0.0000185676,0.002223532,0.0000393124,0.001559542],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01239276,"threshold_uncertainty_score":0.9988521,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005479885856916077,"score_gpt":0.2099350294583228,"score_spread":0.2044551436014067,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}