{"id":"W2957103089","doi":"10.1021/acs.langmuir.9b00875","title":"Synthesis and Solution Behavior of Sulfonate-Based Silicone Surfactants with Specific, Atomically Defined Hydrophobic Tails","year":2019,"lang":"en","type":"article","venue":"Langmuir","topic":"Surfactants and Colloidal Systems","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Government of Shandong Province; National Natural Science Foundation of China; Ministère de l'Économie, de la Science et de l'Innovation - Québec","keywords":"Sulfonate; Pulmonary surfactant; Contact angle; Aqueous solution; Hydrophobic effect; Silicone; Chemical engineering; Dynamic light scattering; Chemistry; Hydrophobe; Polymer chemistry; Materials science; Organic chemistry; Nanotechnology; Nanoparticle; Sodium","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001009551,0.0001831926,0.0003628814,0.00003882047,0.0000454979,0.0000282076,0.0001320711,0.00013365,0.001021905],"category_scores_gemma":[0.00001050111,0.0001443513,0.00005836396,0.0001111325,0.0000625973,0.00006390711,0.0000270139,0.00009612327,0.00005809863],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005304415,"about_ca_system_score_gemma":0.00004211079,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002902136,"about_ca_topic_score_gemma":0.00003991052,"domain_scores_codex":[0.998894,0.00002292392,0.0002639056,0.0003021056,0.0002635075,0.0002536094],"domain_scores_gemma":[0.9992711,0.0001415083,0.0001568235,0.0003003372,0.00005643736,0.00007378495],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002060808,0.00009547669,0.2020895,0.0001129277,0.00002454166,0.00001311173,0.00003482147,0.000004633345,0.7964985,0.00005032308,0.00003349729,0.0008365316],"study_design_scores_gemma":[0.00143297,0.00006839332,0.0934804,0.0001729881,0.00006489813,0.00002093585,0.0001296088,0.0003648862,0.9018939,0.00000706935,0.002012111,0.0003518312],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954935,0.0001730086,0.000006501589,0.00004029374,0.00004749337,0.0001553529,0.0001012695,0.00006237942,0.003920204],"genre_scores_gemma":[0.9989972,0.00001058947,0.0001169118,0.00001281077,0.00002607839,0.00002648566,0.00001601957,0.00003280914,0.0007611253],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1086091,"threshold_uncertainty_score":0.9998913,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009117595064374944,"score_gpt":0.1918239762829433,"score_spread":0.1827063812185683,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}