{"id":"W2959889013","doi":"10.1002/ange.201902752","title":"Mechanische Aktivierung beschleunigt die Hydrolyse der Amidbindung drastisch, vergleichbar der Aktivität von Enzymen","year":2019,"lang":"de","type":"article","venue":"Angewandte Chemie","topic":"Enzyme Structure and Function","field":"Materials Science","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Regina","funders":"Bayerisches Staatsministerium für Bildung und Kultus, Wissenschaft und Kunst; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Molecular biology; Biology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0008929374,0.001060831,0.0011152,0.0002433053,0.0004978165,0.0004700864,0.000837149,0.0009043363,0.005623603],"category_scores_gemma":[0.0001937024,0.0009955284,0.0004008677,0.0005493453,0.0002378556,0.001308438,0.0005735281,0.0009073287,0.006793228],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003258691,"about_ca_system_score_gemma":0.0002977729,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002411954,"about_ca_topic_score_gemma":0.00008841237,"domain_scores_codex":[0.9944116,0.000234311,0.0008978456,0.00172078,0.001115561,0.001619925],"domain_scores_gemma":[0.9969451,0.0002813912,0.0005433853,0.001461793,0.0002538704,0.0005144541],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002367689,0.0001435472,0.001214088,0.0003679838,0.0004092033,0.0001137788,0.001037892,0.00004635944,0.9879634,0.0004250054,0.007451989,0.0005899931],"study_design_scores_gemma":[0.001728349,0.0003122605,0.0006355989,0.0003582606,0.000867996,0.00003199154,0.0002342116,0.0001312898,0.947778,0.0005895052,0.0461656,0.001166912],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9529571,0.01949991,0.0005895535,0.000519629,0.009225057,0.001093251,0.0002029751,0.0003331822,0.01557932],"genre_scores_gemma":[0.9852737,0.0007137225,0.0007605275,0.0007435447,0.002268746,0.00007148515,0.0002661165,0.0001935925,0.009708547],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04018537,"threshold_uncertainty_score":0.9992495,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01030395442823774,"score_gpt":0.2234883497733582,"score_spread":0.2131843953451205,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}