{"id":"W2960856073","doi":"10.1021/acs.joc.9b01259","title":"Aminimide Synthesis Using Concerted Amination Reactions of Alkenes: Scope and Mechanistic Information","year":2019,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies; Government of Ontario; University of Ottawa","keywords":"Hydroamination; Chemistry; Reactive intermediate; Amination; Combinatorial chemistry; Concerted reaction; Reaction mechanism; Hydrazine (antidepressant); Substrate (aquarium); Reaction intermediate; Organic chemistry; Catalysis; Biology; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003453292,0.0001069353,0.0002237245,0.00003328178,0.0000708079,0.00002536103,0.0001824739,0.00009112201,0.002063165],"category_scores_gemma":[0.0005606239,0.00008009704,0.00006237599,0.0001227257,0.00006089872,0.0002872738,0.00003457365,0.000173981,0.000008210258],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001159818,"about_ca_system_score_gemma":0.0001312487,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002337101,"about_ca_topic_score_gemma":6.320887e-7,"domain_scores_codex":[0.9990338,0.00001505571,0.000539594,0.00005885356,0.0002527027,0.00009998608],"domain_scores_gemma":[0.9982732,0.0003700495,0.0008459577,0.0002405027,0.0002196544,0.0000506516],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003274523,0.00002544682,0.0001042795,0.0002211071,0.00007693168,4.741908e-7,0.0001752679,0.00002769576,0.9974505,0.000008805108,0.0000229923,0.001853786],"study_design_scores_gemma":[0.0002465479,0.000008454303,0.0002837799,0.0002971732,0.0002566249,0.0004907001,0.003150065,0.0006149226,0.9941021,0.00006289479,0.0004005186,0.00008626781],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995289,0.0001516464,0.0006228414,0.0000775072,0.00006127625,0.00003375046,0.0000107402,0.000009185834,0.003744041],"genre_scores_gemma":[0.9992943,0.0002889532,0.0001450488,0.000009205263,0.00006564373,7.878539e-7,0.000003281033,0.000011494,0.0001812811],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004005293,"threshold_uncertainty_score":0.9988491,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01052188528362284,"score_gpt":0.2184714184284924,"score_spread":0.2079495331448696,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}