{"id":"W2963351597","doi":"10.1016/j.jct.2019.07.015","title":"An experimental calorimetric and a DFT + U study of the thermodynamic properties of <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" altimg=\"si20.svg\"> <mml:mrow> <mml:msub> <mml:mtext>Cs</mml:mtext> <mml:mn>4</mml:mn> </mml:msub> <mml:mrow> <mml:mfenced open=\"[\" close=\"]\"> <mml:mrow> <mml:mrow> <mml:msub> <mml:mrow> <mml:mfenced open=\"(\" close=\")\"> <mml:mrow> <mml:msub> <mml:mtext>UO</mml:mtext> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:mfenced> </mml:mrow> <mml:mn>4</mml:mn> </mml:msub> <mml:mrow> <mml:mfenced open=\"(\" close=\")\"> <mml:mrow> <mml:msub> <mml:mtext>WO</mml:mtext> <mml:mn>5</mml:mn> </mml:msub> </mml:mrow> </mml:mfenced> </mml:mrow> <mml:mrow> <mml:mfenced open=\"(\" close=\")\"> <mml:mrow> <mml:mrow> <mml:msub> <mml:mtext>W</mml:mtext> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mtext>O</mml:mtext> <mml:mn>8</mml:mn> </mml:msub> </mml:mrow> </mml:mrow> </mml:mfenced> </mml:mrow> <mml:msub> <mml:mtext>O</mml:mtext> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:mrow> </mml:mfenced> </mml:mrow> </mml:mrow> </mml:math> and <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" altimg=\"si21.svg\"> <mml:mrow> <mml:msub> <mml:mtext>Cs</mml:mtext> <mml:mn>4</mml:mn> </mml:msub> <mml:mrow> <mml:mo stretchy=\"false\">[</mml:mo> <mml:msub> <mml:mrow> <mml:mfenced open=\"(\" close=\")\"> <mml:mrow> <mml:msub> <mml:mtext>UO</mml:mtext> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:mfenced> </mml:mrow> <mml:mn>7</mml:mn> </mml:msub> <mml:msub> <mml:mrow> <mml:mfenced open=\"(\" close=\")\"> <mml:mrow> <mml:msub> <mml:mtext>WO</mml:mtext> <mml:mn>5</mml:mn> </mml:msub> </mml:mrow> </mml:mfenced> </mml:mrow> <mml:mn>3</mml:mn> </mml:msub> <mml:msub> <mml:mtext>O</mml:mtext> <mml:mn>3</mml:mn> </mml:msub> <mml:mo stretchy=\"false\">]</mml:mo> </mml:mrow> </mml:mrow> </mml","year":2019,"lang":"lv","type":"article","venue":"The Journal of Chemical Thermodynamics","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"RWTH Aachen University; Canadian Association of Gastroenterology; Austrian Science Fund; Deutsche Forschungsgemeinschaft; Ministry of Education and Science of the Russian Federation; Forschungszentrum Jülich","keywords":"Chemistry; Calorimetry; Enthalpy; Standard enthalpy of formation; Uranyl; Heat capacity; Gibbs free energy; Thermodynamics; Physical chemistry; Analytical Chemistry (journal)","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007408229,0.000993114,0.0008982308,0.001087771,0.00194854,0.0008567635,0.00189728,0.001068939,0.04277428],"category_scores_gemma":[0.002053907,0.0005710563,0.0006201001,0.001599329,0.001286438,0.001471913,0.0009415926,0.002022532,0.002385165],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001342637,"about_ca_system_score_gemma":0.0008756016,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.007190557,"about_ca_topic_score_gemma":0.008599252,"domain_scores_codex":[0.9992072,0.00007948661,0.00002715773,0.000173142,0.0003433295,0.0001697122],"domain_scores_gemma":[0.9993339,0.0002339046,0.0000560662,0.0001562306,0.0001871208,0.00003271192],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00395254,0.001410183,0.009039965,0.005166503,0.0003749011,0.002001011,0.001956064,0.1376501,0.4111204,0.2390998,0.1182576,0.06997088],"study_design_scores_gemma":[0.0001526626,0.001226705,0.01576641,0.0002910906,0.000136889,0.0004994756,0.001190636,0.4998781,0.4269563,0.01678303,0.03682138,0.0002972286],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8669006,0.003011391,0.01642324,0.002539725,0.0009245368,0.0001277865,0.01042486,0.001397779,0.09825006],"genre_scores_gemma":[0.9829876,0.0007905237,0.003618519,0.0002415891,0.00008571071,0.0001318009,0.004278024,0.0002986766,0.007567642],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04277428,"threshold_uncertainty_score":0.1430942,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02309927391781459,"score_gpt":0.2654621916313175,"score_spread":0.2423629177135029,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). 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