{"id":"W2964161631","doi":"10.1039/c9dt00602h","title":"Rh(<scp>i</scp>) and Ru(<scp>ii</scp>) phosphaamidine and phosphaguanidine (1,3-P,N) complexes and their activity for CO<sub>2</sub> hydrogenation","year":2019,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001698348,0.0002377554,0.0002586981,0.0001228152,0.0001396349,0.0002982634,0.0003950764,0.0004817521,0.00104598],"category_scores_gemma":[0.0005092691,0.0001678687,0.000118203,0.0001907408,0.0002611701,0.0002662909,0.0002232135,0.0004036291,0.0002648434],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002969424,"about_ca_system_score_gemma":0.0001036216,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007495929,"about_ca_topic_score_gemma":0.0009827797,"domain_scores_codex":[0.9998271,0.00003765857,0.00001070271,0.00003500877,0.00006271333,0.00002685542],"domain_scores_gemma":[0.999827,0.00003677757,0.00004789226,0.00001945859,0.00002695029,0.00004201116],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000482785,0.00004056561,0.0003652507,0.0001124671,0.00003000675,0.00006340367,0.00004368859,0.0002651853,0.9960492,0.0002885166,0.0001271119,0.002131729],"study_design_scores_gemma":[0.00002162878,0.00038923,0.0008337026,0.000002930245,0.00001303404,0.0001960206,0.00001387464,0.0005219801,0.9963291,0.00003039292,0.001642131,0.000005961218],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.994733,0.001067041,0.001630418,0.00004133685,0.00001466593,0.00003661393,0.000181241,0.00006901018,0.002226555],"genre_scores_gemma":[0.9964157,0.000244067,0.001627431,0.00001539955,0.000004279655,0.00001470979,0.0003097209,0.00001845759,0.001350209],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00104598,"threshold_uncertainty_score":0.00349915,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01074848369197489,"score_gpt":0.2266556016449434,"score_spread":0.2159071179529685,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}