{"id":"W2964466453","doi":"10.15278/isms.2019.tf06","title":"PRODUCT BRANCHING AND LOW TEMPERATURE REACTION KINETICS BY CHIRPED-PULSE FOURIER TRANSFORM MM-WAVE SPECTROSCOPY IN A PULSED UNIFORM SUPERSONIC FLOW","year":2019,"lang":"en","type":"article","venue":"Proceedings of the 74th International Symposium on Molecular Spectroscopy","topic":"Field-Flow Fractionation Techniques","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Fourier transform spectroscopy; Materials science; Branching (polymer chemistry); Fourier transform; Choked flow; Supersonic speed; Spectroscopy; Fourier transform infrared spectroscopy; Pulse (music); Optics; Physics; Thermodynamics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002110548,0.0003297694,0.0002795301,0.0002342946,0.00005286793,0.0001239004,0.0003531809,0.0001746966,0.00005302538],"category_scores_gemma":[0.00004558577,0.000298754,0.0001200148,0.0003197507,0.00004860396,0.000464544,0.0000429,0.000707544,0.000006028449],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004460283,"about_ca_system_score_gemma":0.00002099994,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002869992,"about_ca_topic_score_gemma":0.000008915779,"domain_scores_codex":[0.9982073,0.000008875279,0.0004155582,0.0004256543,0.0006202576,0.0003222951],"domain_scores_gemma":[0.9994648,0.00002311503,0.0001256281,0.000186123,0.0001370188,0.00006330424],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001166651,0.00009776139,0.0004859623,0.0001224899,0.00006262968,0.000001206187,0.0002311934,0.0005337476,0.9966685,0.0007894671,0.000718659,0.0001717428],"study_design_scores_gemma":[0.0007308697,0.0001907781,0.000534364,0.0002211179,0.00001882142,0.00002850365,0.0000443535,0.01786756,0.9785981,0.0007232918,0.0007606932,0.0002815895],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9785264,0.0001031495,0.0002920682,0.003017147,0.0007064297,0.0008652218,0.00005256083,0.0001704152,0.01626666],"genre_scores_gemma":[0.9951398,0.0002586377,0.003901645,0.0001878751,0.0001087859,0.00005747394,0.00003264971,0.00006296801,0.0002501866],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01807041,"threshold_uncertainty_score":0.9999465,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002679185218099213,"score_gpt":0.199538595501125,"score_spread":0.1968594102830258,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}