{"id":"W2964558034","doi":"10.1055/s-0037-1611897","title":"Recent Advances Towards Syntheses of Diterpenoid Alkaloids","year":2019,"lang":"en","type":"article","venue":"Synthesis","topic":"Plant-based Medicinal Research","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; University of Toronto; Austrian Science Fund","keywords":"Chemistry; Terpenoid; Cycloisomerization; Enyne; Total synthesis; Intramolecular force; Stereochemistry; Ring (chemistry); Cycloaddition; Biomimetic synthesis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004226376,0.0008097601,0.0005417038,0.001391958,0.000405901,0.0004624718,0.0004963883,0.0004225457,0.005192752],"category_scores_gemma":[0.0004051522,0.0003730068,0.0004816594,0.00114813,0.0003029359,0.001095205,0.0007421552,0.00133838,0.003065695],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004186177,"about_ca_system_score_gemma":0.0004932473,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003340479,"about_ca_topic_score_gemma":0.0006238923,"domain_scores_codex":[0.9997934,0.00003377387,0.00002596232,0.00005064367,0.00006360954,0.00003262649],"domain_scores_gemma":[0.9998657,0.00003407872,0.00002782721,0.0000185086,0.00003256568,0.00002144934],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002121577,0.0004998967,0.0005114572,0.01774694,0.000210727,0.001577588,0.0008852321,0.004576175,0.4908213,0.01779536,0.007159481,0.4580036],"study_design_scores_gemma":[0.00006520863,0.001154143,0.001719216,0.0007273047,0.0002043974,0.002720224,0.0001841299,0.00172024,0.3244375,0.007084033,0.6598762,0.0001073511],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"review","genre_gemma":"empirical","genre_scores_codex":[0.08184388,0.7957116,0.05851141,0.001397926,0.001080112,0.0003843665,0.001024033,0.0005951933,0.05945146],"genre_scores_gemma":[0.1799136,0.766106,0.03666124,0.0006527603,0.0007370558,0.0001909774,0.001264568,0.0001305019,0.01434331],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.005192752,"threshold_uncertainty_score":0.01737148,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1185534449737654,"score_gpt":0.4441677261358905,"score_spread":0.325614281162125,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}