{"id":"W2967323505","doi":"10.1002/chem.201903064","title":"Underevaluated Solvent Effects in Electrocatalytic CO<sub>2</sub> Reduction by Fe<sup>III</sup> Chloride Tetrakis(pentafluorophenyl)porphyrin","year":2019,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Fundamental Research Funds for the Central Universities; Shaanxi Province Postdoctoral Science Foundation; National Natural Science Foundation of China; Canadian Institute for Theoretical Astrophysics","keywords":"Porphyrin; Benzonitrile; Chemistry; Tetrahydrofuran; Propylene carbonate; Dimethylformamide; Acetonitrile; Solvent; Catalysis; Inorganic chemistry; Chloride; Photochemistry; Solvent effects; Electrocatalyst; Organic chemistry; Physical chemistry; Electrochemistry; Electrode","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003592909,0.0003707729,0.0003078452,0.0001041405,0.0001843488,0.0003672382,0.0002409779,0.000372624,0.0007946562],"category_scores_gemma":[0.0009224965,0.0001857696,0.0001148434,0.0001772604,0.0002861586,0.0003127345,0.0002225192,0.0003037201,0.0001950754],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002496578,"about_ca_system_score_gemma":0.000188131,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00107634,"about_ca_topic_score_gemma":0.001171647,"domain_scores_codex":[0.9996093,0.0001142395,0.00002705381,0.00007070858,0.0001111062,0.00006762139],"domain_scores_gemma":[0.9995616,0.000237436,0.00006753896,0.00002913198,0.00008696233,0.00001725568],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001588692,0.00002109916,0.0003103344,0.00007486317,0.00000681502,0.00009991293,0.00003920816,0.0002457838,0.9973617,0.00003209704,0.00003188066,0.00161754],"study_design_scores_gemma":[0.000001876529,0.00007383082,0.0005235789,0.000002352002,0.000005726586,0.00003677716,0.00001610859,0.0004551406,0.9986331,0.000006590336,0.0002422972,0.0000026029],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971596,0.0007298833,0.001220903,0.00006145975,0.00001242742,0.00001195277,0.00006312934,0.00003570943,0.0007049016],"genre_scores_gemma":[0.997299,0.0005483975,0.001484198,0.00002614638,0.000005415783,0.00001355484,0.00007483462,0.00002508825,0.0005232351],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00107634,"threshold_uncertainty_score":0.002658367,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007665895498432699,"score_gpt":0.2232492158406778,"score_spread":0.2155833203422451,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}