{"id":"W2967706270","doi":"10.1021/jacs.9b05083","title":"Photochemically Cross-Linked Quantum Well Ligands for 2D/3D Perovskite Photovoltaics with Improved Photovoltage and Stability","year":2019,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Perovskite Materials and Applications","field":"Engineering","cited_by":159,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Office of Naval Research; Canadian Institutes of Health Research; Western Economic Diversification Canada; Natural Sciences and Engineering Research Council of Canada; U.S. Navy; Canadian Light Source","keywords":"Chemistry; Perovskite (structure); Photovoltaics; Heterojunction; van der Waals force; Covalent bond; Active layer; Ligand (biochemistry); Chemical engineering; Optoelectronics; Nanotechnology; Layer (electronics); Molecule; Photovoltaic system; Crystallography; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002823969,0.0002319363,0.0004927561,0.00001126871,0.0000786973,0.00009456879,0.0003773157,0.00008854288,0.00002866573],"category_scores_gemma":[0.0000376145,0.0001500546,0.000321514,0.0001945205,0.000383925,0.0001128284,0.00008408589,0.0003586019,0.000001600395],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001328782,"about_ca_system_score_gemma":0.00005455319,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002063106,"about_ca_topic_score_gemma":9.21836e-7,"domain_scores_codex":[0.9987798,0.00000735218,0.0004661519,0.0002123316,0.0002139495,0.0003204663],"domain_scores_gemma":[0.9988061,0.0001656392,0.0003613496,0.0003436702,0.0001783144,0.0001449309],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001361113,0.00005036705,0.002227539,0.0001077873,0.00009773752,1.504545e-7,0.0002129474,0.00004843273,0.9964862,0.00000422069,0.0005356469,0.00009287546],"study_design_scores_gemma":[0.001028159,0.0001360237,0.00173951,0.00003940716,0.00006464045,0.00002251408,0.0001959627,0.01641904,0.9769464,0.0001024882,0.003076091,0.000229813],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982636,0.00006459899,0.0008284164,0.0001149798,0.0001019115,0.0004661974,0.00006500274,0.00004626939,0.0000490047],"genre_scores_gemma":[0.9951762,0.00008575029,0.004172696,0.0002947176,0.000157951,0.00003652517,0.000004591051,0.00004682137,0.00002474439],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01953983,"threshold_uncertainty_score":0.6119051,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006688445869757732,"score_gpt":0.2286420768873188,"score_spread":0.2219536310175611,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}