{"id":"W2968592991","doi":"10.1055/s-0037-1611907","title":"Metal-Catalyzed Site-Selective Monoacylation of Diols in Aqueous Media","year":2019,"lang":"en","type":"article","venue":"Synthesis","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Acylation; Metal ions in aqueous solution; Reagent; Chelation; Phosphate; Aqueous solution; Organic chemistry; Combinatorial chemistry; Diol; Metal; Inorganic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002910211,0.0006513983,0.0003380977,0.0002866261,0.0001558897,0.0003273392,0.0004448674,0.0004629839,0.001131233],"category_scores_gemma":[0.0002394934,0.0002400432,0.0003044249,0.0002886378,0.0002469085,0.0006563153,0.0004645067,0.0007057253,0.001041965],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003403484,"about_ca_system_score_gemma":0.0001907624,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002739065,"about_ca_topic_score_gemma":0.0005267838,"domain_scores_codex":[0.9998358,0.00003184101,0.00001341216,0.00004692029,0.00003832533,0.00003355443],"domain_scores_gemma":[0.9999167,0.00002217217,0.00002535121,0.000009407748,0.00001531586,0.00001105848],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005921821,0.00002116361,0.00006011165,0.0004150717,0.00001523204,0.00009258724,0.00006306512,0.000273017,0.9839616,0.001842349,0.0001328198,0.01306381],"study_design_scores_gemma":[0.000005807845,0.00006357976,0.00006200869,0.000007196081,0.000007377621,0.00007660178,0.00001039466,0.0002370073,0.9912914,0.0001379659,0.008093616,0.000007199252],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6937928,0.0706996,0.2108295,0.0007382304,0.0006428523,0.0003576431,0.0004939154,0.0008309133,0.02161452],"genre_scores_gemma":[0.8738195,0.04547003,0.0576338,0.0003324948,0.00008823643,0.0001870903,0.0003782799,0.0001595867,0.021931],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001131233,"threshold_uncertainty_score":0.003784359,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00525241903348528,"score_gpt":0.2099723152190016,"score_spread":0.2047198961855164,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}