{"id":"W2968810529","doi":"10.1039/c9cc05614a","title":"The synthesis of densely functionalised α-acyloxy enaminals and enaminones<i>via</i>a novel homogeneous silver(<scp>i</scp>) catalysed rearrangement","year":2019,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Chemical synthesis and alkaloids","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Homogeneous; Combinatorial chemistry; Stereochemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002820227,0.0002592824,0.0003863578,0.00003419558,0.0002734097,0.00006934188,0.001271094,0.0001822595,0.00008538389],"category_scores_gemma":[0.001093698,0.0002072895,0.0002085979,0.0002005068,0.000557426,0.00006749159,0.0006730056,0.0003300569,0.00004550132],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008812991,"about_ca_system_score_gemma":0.00004765632,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008845534,"about_ca_topic_score_gemma":0.00001076351,"domain_scores_codex":[0.9983157,0.0000402922,0.0005662229,0.0003673584,0.0003608968,0.0003495351],"domain_scores_gemma":[0.9908325,0.00632114,0.0002660473,0.002237615,0.0001797044,0.0001630052],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001671909,0.0002682753,0.0005952482,0.0000927953,0.0001362112,3.298198e-7,0.0001417883,0.000001456778,0.992985,0.0005424856,0.0003486155,0.004871058],"study_design_scores_gemma":[0.0003741719,0.000008726592,0.000229811,0.00008916375,0.000130845,0.00001956228,0.0004806974,0.0005083555,0.9522001,0.000387936,0.04543658,0.0001341001],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9776306,0.002922461,0.00006443005,0.000708789,0.00003222618,0.0001775945,0.000134396,0.00007192948,0.01825764],"genre_scores_gemma":[0.9965147,0.000644834,0.001081825,0.00007317787,0.00005153437,0.0001595025,0.0001239136,0.00003901308,0.001311457],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04508796,"threshold_uncertainty_score":0.845302,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01867312131854156,"score_gpt":0.2299674563159441,"score_spread":0.2112943349974025,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}