{"id":"W2973230909","doi":"10.1002/0471264229.os096.22","title":"Stereoselective Synthesis of ( <i>R</i> )‐(( <i>R</i> )‐1‐Phenyl‐2,2,2‐Trichloroethyl)2‐(2‐Bromophenyl)aziridine‐1‐Carboxylate","year":2020,"lang":"en","type":"other","venue":"Organic Syntheses","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Aziridine; Chemistry; Moiety; Carbamate; Stereoselectivity; Cleavage (geology); Carboxylate; Combinatorial chemistry; Reagent; Aniline; Nitrene; Organic chemistry; Medicinal chemistry; Ring (chemistry); Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0002121241,0.00120572,0.002097989,0.0003942763,0.0001263837,0.00009454628,0.001358792,0.001025812,0.06564499],"category_scores_gemma":[0.002938047,0.001139013,0.0007164169,0.0008375422,0.0003654067,0.000118633,0.0003321917,0.0007210369,0.001142075],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002091831,"about_ca_system_score_gemma":0.0004032827,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000566441,"about_ca_topic_score_gemma":0.0001018039,"domain_scores_codex":[0.9955846,0.0001095254,0.001074073,0.001419157,0.0009742628,0.0008383874],"domain_scores_gemma":[0.9942394,0.002169528,0.001335596,0.001739223,0.0001092673,0.0004069879],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001832407,0.000881082,0.0003498473,0.002642144,0.00390992,0.00009846959,0.0005180407,0.000001024289,0.4403442,0.0003536207,0.5068446,0.04387383],"study_design_scores_gemma":[0.0002108736,0.00003497889,0.00001320957,0.001709699,0.0009773934,0.00004868552,0.0005076565,0.000009597163,0.5203298,0.00008469672,0.4750471,0.001026311],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.0004339929,0.003278457,0.00008898525,0.0003949775,0.0006518079,0.0003361235,0.001156438,0.001022339,0.9926369],"genre_scores_gemma":[0.4558265,0.004535249,0.0009566694,0.0002701503,0.002923848,0.0003861704,0.0001253019,0.004429876,0.5305462],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.4620907,"threshold_uncertainty_score":0.9996356,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01360920661734986,"score_gpt":0.2152647678341954,"score_spread":0.2016555612168456,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}