{"id":"W2974704837","doi":"10.1002/ejoc.201900993","title":"Phenoxy‐Dialkoxy Borates as a New Class of Readily Prepared Preactivated Reagents for Base‐Free Cross‐Coupling","year":2019,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Reagent; Adduct; Boronic acid; Base (topology); Boron; Combinatorial chemistry; Solubility; Organic chemistry; Coupling reaction; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003348671,0.000790271,0.000353714,0.0003707508,0.0001933376,0.0002945774,0.0004045872,0.0005272889,0.001775384],"category_scores_gemma":[0.0001552069,0.0003424186,0.0001909036,0.00022484,0.0002337847,0.0005016061,0.0003465441,0.0007701325,0.001244274],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002299522,"about_ca_system_score_gemma":0.0002381499,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002097319,"about_ca_topic_score_gemma":0.0004362805,"domain_scores_codex":[0.9997908,0.00004751662,0.0000177975,0.00005635613,0.00004678383,0.00004074954],"domain_scores_gemma":[0.9999036,0.00001812155,0.00003145624,0.00001413784,0.00001164647,0.00002107277],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008151068,0.00002224919,0.0000513586,0.000175987,0.000008265484,0.0001050282,0.00003039213,0.0001440415,0.9934341,0.0009491506,0.0001628069,0.004835123],"study_design_scores_gemma":[0.00002477193,0.0002873369,0.0002921901,0.000009636477,0.00001434146,0.0004057513,0.000009088522,0.0003691856,0.9832199,0.0001500121,0.01520407,0.00001384439],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7644203,0.04478655,0.1651575,0.0006960981,0.0003801134,0.0003796451,0.001164666,0.001253205,0.02176196],"genre_scores_gemma":[0.921074,0.01354597,0.05047469,0.0003886667,0.000108862,0.0002001618,0.001032958,0.0001859471,0.01298877],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001775384,"threshold_uncertainty_score":0.005939245,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01377897754707321,"score_gpt":0.2568689991225904,"score_spread":0.2430900215755172,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}