{"id":"W2976541695","doi":"10.1016/j.jorganchem.2019.120962","title":"Stereochemistry of oxidative addition of methyl iodide and hydrogen peroxide to organoplatinum(II) complexes having an appended phenol group and the supramolecular chemistry of the platinum(IV) products","year":2019,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Oxidative addition; Intramolecular force; Hydrogen bond; Medicinal chemistry; Isomerization; Supramolecular chemistry; Platinum; Iodide; Hydrogen peroxide; Stereochemistry; Methyl iodide; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001740116,0.0002011671,0.0001094303,0.0001997646,0.0001655508,0.0002823873,0.0005028278,0.0002699752,0.005221473],"category_scores_gemma":[0.0002811736,0.0001690082,0.000118582,0.0001183662,0.0003956751,0.0002820553,0.0001683033,0.0003642803,0.0004711715],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004741864,"about_ca_system_score_gemma":0.0002916419,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001206416,"about_ca_topic_score_gemma":0.001925509,"domain_scores_codex":[0.999897,0.00001049679,0.000005515584,0.00002382854,0.00002494139,0.00003827468],"domain_scores_gemma":[0.9998467,0.00002665005,0.00004666439,0.00002212319,0.00003022088,0.00002747059],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000658691,0.00001879133,0.0003016458,0.00003122319,0.000006678978,0.0001224848,0.00006671126,0.000153437,0.994841,0.001202035,0.0001219395,0.00247547],"study_design_scores_gemma":[0.00001442244,0.0001206002,0.001553715,0.000002198423,0.000005265576,0.0000441381,0.00002452709,0.0002964687,0.9971523,0.0001057483,0.0006765787,0.000003985118],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9867138,0.000501558,0.002457825,0.0001137181,0.00005081991,0.00001558551,0.0002532586,0.0001137214,0.009779772],"genre_scores_gemma":[0.9981906,0.0001110154,0.000273419,0.00001488635,0.000002954715,0.000004326924,0.0001046138,0.0000109181,0.001287304],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005221473,"threshold_uncertainty_score":0.01746762,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007561486544940579,"score_gpt":0.2014140416569613,"score_spread":0.1938525551120208,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}