{"id":"W2976637803","doi":"10.1002/chem.201903931","title":"The Role of LiBr and ZnBr<sub>2</sub> on the Cross‐Coupling of Aryl Bromides with Bu<sub>2</sub>Zn or BuZnBr","year":2019,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Eli Lilly and Company","keywords":"Chemistry; Aryl; Electrophile; Catalysis; Bromide; Adduct; Nucleophile; Alkyl; Medicinal chemistry; Negishi coupling; Lewis acids and bases; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003926782,0.0005457189,0.0003938152,0.0001402665,0.0001411312,0.0004402152,0.0003892484,0.0003622418,0.002173938],"category_scores_gemma":[0.0005345899,0.0002854567,0.0001452426,0.0001688954,0.0003290931,0.0003335289,0.000324951,0.0002854894,0.000656411],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002116933,"about_ca_system_score_gemma":0.0001976253,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001078102,"about_ca_topic_score_gemma":0.002066702,"domain_scores_codex":[0.9997726,0.00006072283,0.00002024323,0.00003464723,0.00004030618,0.0000715225],"domain_scores_gemma":[0.9997153,0.0001068499,0.00007571497,0.00002365019,0.00003550257,0.0000429772],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007531853,0.00005413103,0.0002214112,0.0001383553,0.00002773624,0.0001113968,0.00007986129,0.0002357034,0.9940948,0.000153862,0.00007106147,0.004058473],"study_design_scores_gemma":[0.00001308473,0.000141995,0.0003643644,0.000004181117,0.00001601522,0.00002916502,0.00001307405,0.0002171126,0.9986749,0.000008886866,0.0005127632,0.000004486634],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940797,0.001225971,0.001302217,0.00003813763,0.00002185169,0.0000239799,0.00008441407,0.000112159,0.003111659],"genre_scores_gemma":[0.9962514,0.000863123,0.0008399856,0.00003659485,0.000006746429,0.00001272997,0.00007464424,0.00004136478,0.001873477],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002173938,"threshold_uncertainty_score":0.007272542,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008063857548714455,"score_gpt":0.2115497307625508,"score_spread":0.2034858732138363,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}