{"id":"W2976646412","doi":"10.1021/acs.chemmater.9b02287","title":"Tuning Electrical, Optical, and Thermal Properties through Cation Disorder in Cu<sub>2</sub>ZnSnS<sub>4</sub>","year":2019,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Chalcogenide Semiconductor Thin Films","field":"Engineering","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Renewable Energy Laboratory; Canadian Light Source; Basic Energy Sciences; Army Research Office; U.S. Department of Energy; Office of Energy Efficiency and Renewable Energy; Argonne National Laboratory; SLAC National Accelerator Laboratory; Massachusetts Institute of Technology; Division of Materials Research; Office of Science; National Science Foundation","keywords":"CZTS; Kesterite; Materials science; Semiconductor; Stacking; Band gap; X-ray absorption spectroscopy; Chemical vapor deposition; Ternary operation; Absorption spectroscopy; Analytical Chemistry (journal); Chemical engineering; Optoelectronics; Chemistry; Optics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000544529,0.0002235749,0.0001357212,0.0001931697,0.00019741,0.0003902244,0.0002784499,0.0001463715,0.0004703859],"category_scores_gemma":[0.0001512586,0.0001385539,0.00005393944,0.0002639556,0.0003154532,0.0002735414,0.0001249088,0.0001191892,0.0001007036],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005201577,"about_ca_system_score_gemma":0.0001807913,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00193521,"about_ca_topic_score_gemma":0.003676669,"domain_scores_codex":[0.9999461,0.000005278355,0.000003066866,0.00001617672,0.00001970257,0.000009602049],"domain_scores_gemma":[0.9999454,0.0000119698,0.00002126685,0.000004803097,0.00001235899,0.000004157337],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004959557,0.000008096355,0.0008357206,0.00004087245,0.000005599363,0.00004003923,0.00001599049,0.001240372,0.9961467,0.0002500885,0.00005302586,0.001313817],"study_design_scores_gemma":[0.000007578529,0.00004832112,0.00277696,0.000002721084,0.000008591966,0.00007757122,0.00004759285,0.006306877,0.9894695,0.0001245441,0.001125836,0.000003854603],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976292,0.0004398676,0.001190424,0.00002826707,0.00000567052,0.000003832689,0.00006265657,0.00002767105,0.0006123108],"genre_scores_gemma":[0.9980159,0.000237759,0.001045563,0.000007261165,0.000002120047,0.000005099332,0.00006105182,0.000008867021,0.0006163632],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00193521,"threshold_uncertainty_score":0.003847837,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0111815889340259,"score_gpt":0.1957632136699251,"score_spread":0.1845816247358992,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}