{"id":"W2976779337","doi":"10.1021/acs.macromol.9b01381","title":"Chromium Amino-bis(phenolate) Complexes as Catalysts for Ring-Opening Polymerization of Cyclohexene Oxide","year":2019,"lang":"en","type":"article","venue":"Macromolecules","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada; Memorial University of Newfoundland; Research and Development Corporation of Newfoundland and Labrador; Canada Foundation for Innovation","keywords":"Cyclohexene oxide; Chemistry; Polymer chemistry; Polymerization; Ligand (biochemistry); Catalysis; Protonation; Oxide; Cyclohexene; Chromium; Medicinal chemistry; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001211975,0.0002585174,0.0004563824,0.0001899644,0.00004765079,0.00004155487,0.0003477886,0.0001239257,0.0001507621],"category_scores_gemma":[0.0001841299,0.0002884037,0.0002031688,0.0003995233,0.00005645072,0.0001429453,0.0001504793,0.00009873074,0.00006590085],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008088997,"about_ca_system_score_gemma":0.00004237609,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003211041,"about_ca_topic_score_gemma":0.00001205191,"domain_scores_codex":[0.9983464,0.00002114857,0.0005518989,0.0004283916,0.0003029127,0.0003491931],"domain_scores_gemma":[0.9988449,0.0001541084,0.0002435018,0.0005256835,0.0001359029,0.0000959657],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004201186,0.00003306222,0.00127729,0.0001905909,0.0001119715,0.000002425205,0.0001640802,0.004428325,0.9884341,0.005009256,0.00004861051,0.0002582493],"study_design_scores_gemma":[0.0007940695,0.00003337671,0.0008006573,0.00009057301,0.00006545651,0.00001183166,0.0001010549,0.02147795,0.9756728,0.0001165457,0.000522687,0.0003130441],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.973831,0.0003011129,0.02103309,0.00005295573,0.0001523368,0.000400392,0.00008127839,0.0001760241,0.003971818],"genre_scores_gemma":[0.9963893,0.000009924813,0.00206392,0.00006058119,0.00005054311,0.00004686099,0.0004545039,0.00008638146,0.0008379895],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0225583,"threshold_uncertainty_score":0.9999568,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008219252381634685,"score_gpt":0.2380045065952912,"score_spread":0.2297852542136566,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}