{"id":"W2978564267","doi":"10.1039/c9ra07527e","title":"Synthesis and reactivity of 2-thionoester pyrroles: a route to 2-formyl pyrroles","year":2019,"lang":"en","type":"article","venue":"RSC Advances","topic":"Synthesis and Characterization of Pyrroles","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Reactivity (psychology); Chemistry; Deuterium; Combinatorial chemistry; Medicinal chemistry; Pyrrole; Organic chemistry; Physics; Medicine","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001108515,0.0001868124,0.0003519173,0.00006689413,0.00004771142,0.00003228322,0.0001732659,0.00009005692,0.0007120723],"category_scores_gemma":[0.0001169538,0.0001617276,0.0000703698,0.00008382412,0.000053512,0.0004151773,0.00007300224,0.00007659707,0.00006811321],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002346866,"about_ca_system_score_gemma":0.00002206645,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001316057,"about_ca_topic_score_gemma":0.00001938714,"domain_scores_codex":[0.9989395,0.00001662965,0.0002801772,0.0003351655,0.00021771,0.0002108525],"domain_scores_gemma":[0.9990789,0.0002430322,0.0001896062,0.0003380459,0.00005517368,0.00009528585],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001227472,0.0001003144,0.05479594,0.0003357948,0.0000374179,0.000001547698,0.0004217395,0.00002570789,0.8328449,0.0004060794,0.0000315869,0.1108763],"study_design_scores_gemma":[0.0002095855,0.00002953441,0.01874058,0.0003477796,0.00002941971,0.000005360829,0.0009147421,0.00006524147,0.9126589,0.0001607841,0.06655393,0.0002841518],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9883631,0.0003912499,0.000116188,0.0003322355,0.0000640374,0.00007999927,0.00007094024,0.00005748179,0.01052474],"genre_scores_gemma":[0.9976873,0.0003261037,0.0006264042,0.000116468,0.00007869057,0.00002979968,0.000006628528,0.000025833,0.001102777],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1105921,"threshold_uncertainty_score":0.7796692,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00828381548454012,"score_gpt":0.2320737599193985,"score_spread":0.2237899444348583,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}