{"id":"W2979397458","doi":"10.1021/acs.jpcc.9b08005","title":"Unraveling Polymorphic Pyrrhotite Electrochemical Oxidation by Underlying Electronic Structures","year":2019,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Metal Extraction and Bioleaching","field":"Engineering","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Pyrrhotite; Monoclinic crystal system; X-ray photoelectron spectroscopy; Chemistry; Polysulfide; Electrochemistry; Metal; Sulfide; Crystallography; Inorganic chemistry; Physical chemistry; Chemical engineering; Crystal structure; Electrode; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001678893,0.0001248043,0.0001665563,0.0000143456,0.00003906612,0.00002719395,0.0002014629,0.0000541174,0.00009427545],"category_scores_gemma":[0.00002119229,0.00008456568,0.0001022128,0.00009709714,0.00001833495,0.0001140065,0.00001173169,0.0007168165,0.00001338128],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009508244,"about_ca_system_score_gemma":0.00002519955,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000145696,"about_ca_topic_score_gemma":9.373819e-8,"domain_scores_codex":[0.9992657,0.00002061393,0.0002055103,0.00006490059,0.0002230249,0.0002202863],"domain_scores_gemma":[0.9995975,0.00008895832,0.0001087805,0.0001127864,0.0000330014,0.00005897619],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002130342,0.00001310198,0.000005786844,0.00003139541,0.00004880248,2.568262e-7,0.00005119229,0.001705102,0.9973423,0.0000697195,0.00009996741,0.0006109985],"study_design_scores_gemma":[0.000191644,0.00003142935,0.00003070929,0.0000216337,0.0000357449,0.00006077049,0.00006240665,0.01241976,0.9855729,0.000867276,0.0006004284,0.0001052738],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961291,0.0004215219,0.002344053,0.0000680556,0.00005054511,0.00003265226,6.74078e-7,0.00003120942,0.0009221722],"genre_scores_gemma":[0.9994814,0.00004568363,0.00002475894,0.00002966133,0.0002796118,2.793296e-7,0.000004823209,0.00001769561,0.0001160249],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01176945,"threshold_uncertainty_score":0.3448488,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005979540795047939,"score_gpt":0.2197963860386763,"score_spread":0.2138168452436284,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}