{"id":"W2979436549","doi":"10.1002/adsc.201901047","title":"Reaction of Cycloalkene‐1‐carboxamides with Aryl Boronates via Rhodium(III)‐Catalyzed C−H Activation: A Versatile Route to 3,4‐Cycloalkaquinolin‐2(1<i>H</i>)‐ones","year":2019,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Science Foundation of Tianjin City; National Natural Science Foundation of China; McGill University","keywords":"Chemistry; Rhodium; Pinacol; Aryl; Catalysis; Cycloalkene; Surface modification; Combinatorial chemistry; Medicinal chemistry; Organic chemistry; Alkyl","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004127785,0.0006001743,0.001036804,0.0003720266,0.000169043,0.00005258371,0.0005410205,0.000238022,0.00129272],"category_scores_gemma":[0.0004624905,0.000582546,0.0003334444,0.001374193,0.0001415601,0.0008861757,0.000164811,0.0002394149,0.0001831445],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005208458,"about_ca_system_score_gemma":0.0001698575,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00132288,"about_ca_topic_score_gemma":0.0002174469,"domain_scores_codex":[0.9963207,0.00005430766,0.0009501678,0.001143997,0.0009809539,0.0005499191],"domain_scores_gemma":[0.9954434,0.001375413,0.0007777683,0.001660709,0.0004953233,0.0002473661],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001099772,0.0002061063,0.005178113,0.0002818299,0.0007185095,0.00000432819,0.000414077,0.005471311,0.9522696,0.00009440693,0.00003464911,0.03422732],"study_design_scores_gemma":[0.001091794,0.00004449887,0.005466,0.0004172164,0.000558687,0.00002361859,0.001381312,0.0005345198,0.9867144,0.000150689,0.002905211,0.0007121145],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9830636,0.0001661111,0.01192247,0.0003114023,0.0001806546,0.0004228055,0.0001183611,0.0002926085,0.00352199],"genre_scores_gemma":[0.9835178,0.00007077613,0.01389908,0.00007817703,0.0001305643,0.000367887,0.0007279604,0.0001274369,0.001080301],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03444477,"threshold_uncertainty_score":0.9996626,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008092189354246297,"score_gpt":0.2401806264767699,"score_spread":0.2320884371225236,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}