{"id":"W2980125436","doi":"10.1002/anie.201909806","title":"The Fundamentals of Real‐Time Surface Plasmon Resonance/Electrogenerated Chemiluminescence","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval; Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; Ministero degli Affari Esteri e della Cooperazione Internazionale; Ministère des relations internationales et de la Francophonie","keywords":"Luminophore; Surface plasmon resonance; Electrochemiluminescence; Excited state; Plasmon; Surface plasmon; Photochemistry; Localized surface plasmon; Resonance (particle physics); Cyclic voltammetry; Luminescence; Chemiluminescence; Chemistry; Materials science; Surface plasmon polariton; Electron transfer; Analytical Chemistry (journal); Optoelectronics; Electrode; Electrochemistry; Nanotechnology; Atomic physics; Nanoparticle; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001616302,0.0001154851,0.0001091524,0.0000192246,0.00005651542,0.00002080104,0.0001998566,0.00009913417,0.00001778173],"category_scores_gemma":[0.00005186838,0.00008928854,0.000088072,0.00009572633,0.00009000043,0.000009586451,0.00005787916,0.00006194149,0.000009418346],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004054306,"about_ca_system_score_gemma":0.00003129535,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001671781,"about_ca_topic_score_gemma":0.000006618532,"domain_scores_codex":[0.999163,0.00001613021,0.0002143507,0.0002443267,0.0002205766,0.000141593],"domain_scores_gemma":[0.9993213,0.00002552633,0.000166436,0.000215324,0.0002447592,0.00002667414],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001104462,0.00002923887,0.0007563253,0.000003744152,0.00004836256,4.652217e-7,0.000005218002,0.000006428246,0.9915565,0.00003063019,0.00708536,0.0003673339],"study_design_scores_gemma":[0.0002062901,0.00008120755,0.0002021793,0.00002541091,0.00001001439,0.000006708075,0.00002092574,0.00009486838,0.9828428,0.00006131597,0.01634202,0.0001062277],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957919,0.0002062275,0.0001270446,0.0003142799,0.0002056067,0.0001113132,0.00006133892,0.00002733829,0.003154926],"genre_scores_gemma":[0.9943138,0.001237555,0.0005178744,0.00007434204,0.0002887849,0.000005669142,0.000797342,0.00001257423,0.002752087],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009256662,"threshold_uncertainty_score":0.3641081,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005968966318268901,"score_gpt":0.2516722374557568,"score_spread":0.2457032711374879,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}