{"id":"W2982137197","doi":"10.1039/c9cc07481c","title":"Synthesis of C-terminal glycopeptides<i>via</i>oxime resin aminolysis","year":2019,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada","keywords":"Aminolysis; Glycopeptide; Oxime; Chemistry; Combinatorial chemistry; Terminal (telecommunication); Organic chemistry; Stereochemistry; Computer science; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001501996,0.0002270743,0.0004485872,0.00004998405,0.00008961219,0.00002588111,0.001731758,0.0002337896,0.002488374],"category_scores_gemma":[0.0003510761,0.0002380558,0.0002901632,0.0002706801,0.0003655647,0.0001027077,0.0005564366,0.0003661042,0.0003346585],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009548121,"about_ca_system_score_gemma":0.00005496258,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006752873,"about_ca_topic_score_gemma":0.000002900513,"domain_scores_codex":[0.9985418,0.00003914015,0.0005578351,0.0003286963,0.0002501172,0.0002824115],"domain_scores_gemma":[0.9948078,0.001249091,0.0002362331,0.003450819,0.0001262302,0.0001298361],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003465828,0.0002202771,0.00106436,0.0001783633,0.00007544499,0.000001483242,0.0000710174,0.000001261974,0.9942843,0.0001549821,0.0002794767,0.003634341],"study_design_scores_gemma":[0.0001770236,0.000003844305,0.00004723378,0.0001591932,0.0001154494,0.00001924874,0.0001604351,0.0004268202,0.9942295,0.0002437089,0.004160809,0.0002567566],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.832293,0.0003380342,0.00001012596,0.0003699238,0.00001582039,0.00005731744,0.00006597454,0.00008924322,0.1667606],"genre_scores_gemma":[0.9950799,0.0001177492,0.002004365,0.00003542475,0.00004257771,0.00007211312,0.00009846068,0.00003409991,0.002515336],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1642452,"threshold_uncertainty_score":0.9984235,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01886143057325317,"score_gpt":0.2468795438642786,"score_spread":0.2280181132910254,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}