{"id":"W2983212862","doi":"10.1016/j.phytochem.2019.112188","title":"Unveiling fungal detoxification pathways of the cruciferous phytoalexin rapalexin A: Sequential L-cysteine conjugation, acetylation and oxidative cyclization mediated by Colletotrichum spp.","year":2019,"lang":"en","type":"article","venue":"Phytochemistry","topic":"Genomics, phytochemicals, and oxidative stress","field":"Biochemistry, Genetics and Molecular Biology","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Biology; Glucosinolate; Phytoalexin; Botrytis cinerea; Biochemistry; Plant defense against herbivory; Myrosinase; Isothiocyanate; Cysteine; Pathogen; Colletotrichum; Microbiology; Botany; Gene; Enzyme; Brassica","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001932092,0.0002546573,0.000260547,0.00002910442,0.0001081803,0.00002632105,0.0002469654,0.0002552417,0.00004758819],"category_scores_gemma":[0.0002286585,0.0002366492,0.00009542323,0.0002129182,0.0001952058,0.00001636095,0.0001296916,0.0001514576,0.000009464293],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004664286,"about_ca_system_score_gemma":0.0001087196,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008707355,"about_ca_topic_score_gemma":0.000003888864,"domain_scores_codex":[0.998452,0.00009496382,0.0004559639,0.0005320043,0.0002253132,0.0002397525],"domain_scores_gemma":[0.9986326,0.00004873582,0.0004774182,0.000474544,0.000286532,0.00008018895],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001252054,0.00006777311,0.01361223,0.0001186943,0.00006227729,1.513227e-7,0.0001039151,0.00008896372,0.9849125,0.00002629002,0.0007779799,0.0001039856],"study_design_scores_gemma":[0.001207464,0.00008225811,0.004357324,0.00005075718,0.00003146009,0.000005627168,0.0001758244,0.000381731,0.9926324,0.0001677692,0.0006560802,0.0002513209],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9947796,0.001130015,0.00173803,0.00009172992,0.0001442288,0.0005907798,0.0002883915,0.00001879062,0.001218393],"genre_scores_gemma":[0.9975803,0.0001564905,0.0002562781,0.00008895284,0.0001876686,0.00004706658,0.001187503,0.00003133786,0.0004644397],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009254906,"threshold_uncertainty_score":0.9650274,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008084892523865248,"score_gpt":0.214086937794798,"score_spread":0.2060020452709327,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}