{"id":"W2983212862","doi":"10.1016/j.phytochem.2019.112188","title":"Unveiling fungal detoxification pathways of the cruciferous phytoalexin rapalexin A: Sequential L-cysteine conjugation, acetylation and oxidative cyclization mediated by Colletotrichum spp.","year":2019,"lang":"en","type":"article","venue":"Phytochemistry","topic":"Genomics, phytochemicals, and oxidative stress","field":"Biochemistry, Genetics and Molecular Biology","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Biology; Glucosinolate; Phytoalexin; Botrytis cinerea; Biochemistry; Plant defense against herbivory; Myrosinase; Isothiocyanate; Cysteine; Pathogen; Colletotrichum; Microbiology; Botany; Gene; Enzyme; Brassica","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001626539,0.0003116962,0.0001694513,0.0001890738,0.0002346905,0.0003756088,0.0001732315,0.0003098368,0.0006514358],"category_scores_gemma":[0.00009073566,0.000108187,0.0002305019,0.0001531361,0.0002443015,0.0006416249,0.0002355494,0.0005260998,0.0002673727],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004279238,"about_ca_system_score_gemma":0.0004069463,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001656441,"about_ca_topic_score_gemma":0.00509121,"domain_scores_codex":[0.9999511,0.000006877338,0.000003352917,0.00001433352,0.000008345604,0.00001597854],"domain_scores_gemma":[0.9999148,0.00001066818,0.00002728072,0.00001116998,0.00001605554,0.00002000439],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001327076,0.00001464394,0.0004773725,0.00003428807,0.000005057664,0.00004285396,0.00003205343,0.00007267873,0.996992,0.000205053,0.00003128683,0.001959805],"study_design_scores_gemma":[0.00002822046,0.0004880918,0.03151338,0.00001911755,0.000048646,0.000464153,0.000346169,0.002641364,0.9555614,0.001141425,0.007725515,0.00002253719],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9920567,0.002009892,0.004342331,0.0003245385,0.00001495994,0.00001606134,0.0002489294,0.00006793504,0.0009186221],"genre_scores_gemma":[0.9919822,0.001611714,0.00422893,0.000105291,0.00001464043,0.00001039752,0.0007173083,0.00001599539,0.001313612],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001656441,"threshold_uncertainty_score":0.003293514,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008084892523865248,"score_gpt":0.214086937794798,"score_spread":0.2060020452709327,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}