{"id":"W2983902613","doi":"10.1021/acs.cgd.9b01477","title":"Real-Time in Situ Monitoring of Particle and Structure Evolution in the Mechanochemical Synthesis of UiO-66 Metal–Organic Frameworks","year":2019,"lang":"en","type":"article","venue":"Crystal Growth & Design","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":68,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Hrvatska Zaklada za Znanost; Defense Threat Reduction Agency; Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung; Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada; European Cooperation in Science and Technology","keywords":"Mechanochemistry; Synchrotron; Crystallite; Metal-organic framework; Diffraction; In situ; Particle (ecology); Materials science; Nanotechnology; Kinetics; Powder diffraction; Particle size; X-ray crystallography; Chemical engineering; Metal; Chemistry; Crystallography; Metallurgy; Physical chemistry; Organic chemistry; Physics; Engineering; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00015984,0.000133946,0.0001477919,0.0001239391,0.0001302656,0.0003177147,0.000219509,0.0002133159,0.0005471183],"category_scores_gemma":[0.0001991915,0.0001290266,0.00007764576,0.0001419358,0.000227459,0.0002472251,0.0001467062,0.0002746822,0.00008792942],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003712017,"about_ca_system_score_gemma":0.0001387298,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001660339,"about_ca_topic_score_gemma":0.002778774,"domain_scores_codex":[0.9999068,0.000007709731,0.000003644473,0.00002663529,0.0000325559,0.00002264689],"domain_scores_gemma":[0.9999088,0.00002686274,0.00002843056,0.000009612942,0.00001405395,0.0000121576],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006890698,0.00001436336,0.0003681514,0.00002295678,0.000002931124,0.00002803525,0.00004813676,0.0003369256,0.9961747,0.000164701,0.00005310337,0.002717009],"study_design_scores_gemma":[0.000004237426,0.0000324001,0.001677308,0.0000015312,0.000001977116,0.00001985961,0.00003007869,0.004019007,0.9936422,0.00002925473,0.0005372617,0.000004946156],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935548,0.0003630271,0.004613096,0.00004980768,0.000014378,0.00001042724,0.000192241,0.0001232518,0.00107904],"genre_scores_gemma":[0.9955541,0.0001540391,0.003660176,0.000009329839,0.000003400201,0.000008396779,0.00006458847,0.00001148254,0.0005344026],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001660339,"threshold_uncertainty_score":0.003301382,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01002201682926115,"score_gpt":0.2198246739175658,"score_spread":0.2098026570883047,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}