{"id":"W2985771015","doi":"10.1002/ange.201984862","title":"Frontispiz: Strong Enhancement of π‐Electron Donor/Acceptor Ability by Complementary DD/AA Hydrogen Bonding","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Hydrogen bond; Chemistry; Acceptor; Electron acceptor; Electron donor; Crystallography; Photochemistry; Molecule; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009524119,0.0002184344,0.000288339,0.00004512248,0.00007168939,0.00002148014,0.000246408,0.00009205754,0.007338217],"category_scores_gemma":[0.000009572309,0.0002346132,0.00024328,0.0001052139,0.0000583728,0.000130716,0.00009712767,0.0002128905,0.00001981752],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001634339,"about_ca_system_score_gemma":0.00003103995,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002754814,"about_ca_topic_score_gemma":0.00005361212,"domain_scores_codex":[0.998589,0.00001200582,0.0003733989,0.0004023258,0.0002444912,0.0003787316],"domain_scores_gemma":[0.9991577,0.00004454056,0.0001811907,0.0004735789,0.00005167451,0.00009134334],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005566452,0.0002076963,0.005996638,0.0001375989,0.0002051375,0.000001174349,0.0001422882,0.000002657166,0.9831128,0.00004512953,0.00993482,0.0001583547],"study_design_scores_gemma":[0.0006365946,0.00005117121,0.00005086845,0.00003944144,0.00006117529,0.000002402566,0.0003530114,0.000005391601,0.9104348,0.0000522934,0.0881063,0.0002065433],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9737993,0.0006412281,0.0001186841,0.000102146,0.0001011509,0.0001621464,0.0002547835,0.0000466485,0.02477393],"genre_scores_gemma":[0.997053,0.00003557457,0.0001926805,0.0000717955,0.00006204767,0.00004086472,0.0008303467,0.00002536107,0.001688291],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07817148,"threshold_uncertainty_score":0.9935692,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009293620962911866,"score_gpt":0.2514712548258574,"score_spread":0.2421776338629455,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}