{"id":"W2986377711","doi":"10.1002/anie.201910288","title":"Strong Enhancement of π‐Electron Donor/Acceptor Ability by Complementary DD/AA Hydrogen Bonding","year":2019,"lang":"en","type":"review","venue":"Angewandte Chemie International Edition","topic":"Organic and Molecular Conductors Research","field":"Materials Science","cited_by":75,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Stacking; Ambipolar diffusion; Acceptor; Supramolecular chemistry; Molecule; Electron acceptor; Carbazole; Hydrogen bond; Materials science; Chemical physics; Photochemistry; Crystallography; Chemistry; Electron; Crystal structure","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004884012,0.0003220852,0.0007425059,0.0001379008,0.00006470696,0.00006490709,0.0006803072,0.000174563,0.006912809],"category_scores_gemma":[0.0000707881,0.000297136,0.0003069259,0.0001306808,0.00009929689,0.0002606997,0.0002711092,0.0002702641,0.0002141812],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008241825,"about_ca_system_score_gemma":0.0002824391,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001059215,"about_ca_topic_score_gemma":0.000005536474,"domain_scores_codex":[0.9973435,0.00009479689,0.0007455613,0.0005880584,0.0008672444,0.0003608499],"domain_scores_gemma":[0.998744,0.0001114014,0.0005150972,0.0003552287,0.0001863931,0.00008787619],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002230495,0.0002078956,0.00000589536,0.003248011,0.0002345232,0.000002609503,0.00005301586,2.764725e-7,0.9392222,0.0001875247,0.0401249,0.01669085],"study_design_scores_gemma":[0.0001469824,0.00004635234,2.658696e-7,0.0005092063,0.0000869016,0.000003265767,0.00001407002,9.053545e-7,0.5503728,0.00002613216,0.4486505,0.0001426784],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.007356995,0.9798167,0.001453534,0.000204462,0.003085093,0.001467202,0.002996104,0.00006422983,0.00355563],"genre_scores_gemma":[0.02347775,0.9594088,0.0002254628,0.00006875009,0.001527432,0.0002214066,0.01311017,0.00008488068,0.00187542],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.4085256,"threshold_uncertainty_score":0.9999481,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05156295177589271,"score_gpt":0.3572452079282054,"score_spread":0.3056822561523126,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}