{"id":"W2988039790","doi":"10.3390/md17110643","title":"Novel Microcystins from Planktothrix prolifica NIVA-CYA 544 Identified by LC-MS/MS, Functional Group Derivatization and 15N-labeling","year":2019,"lang":"en","type":"article","venue":"Marine Drugs","topic":"Aquatic Ecosystems and Phytoplankton Dynamics","field":"Environmental Science","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"European Commission","keywords":"Chemistry; Derivatization; Microcystin; Stereochemistry; Mass spectrometry; Amino acid; Cyanobacteria; Chromatography; Biochemistry; Bacteria; Biology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006956906,0.0007583444,0.000332999,0.0005389081,0.0002647831,0.0003420643,0.0001509201,0.0002908999,0.0002831333],"category_scores_gemma":[0.0001261727,0.0001585955,0.0002786238,0.0003328507,0.0002844233,0.0002057487,0.0003009014,0.0003172864,0.000185135],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004427174,"about_ca_system_score_gemma":0.0004089302,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003147688,"about_ca_topic_score_gemma":0.00382843,"domain_scores_codex":[0.99991,0.000005062907,0.00000763813,0.00002923595,0.0000338403,0.00001424928],"domain_scores_gemma":[0.9999059,0.00001207051,0.00002983227,0.000008261252,0.00002641539,0.00001741461],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002704844,0.000002550997,0.0003241163,0.00001345484,0.00000273123,0.00006379354,0.00001043869,0.00002113739,0.9989366,0.000007719774,0.000005364795,0.0005850813],"study_design_scores_gemma":[0.00001299538,0.0002359388,0.04334731,0.000008364646,0.0000597218,0.0007574983,0.00008065008,0.0007401456,0.9519575,0.00006995422,0.002715018,0.00001476496],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955564,0.0008017456,0.00161003,0.00004687236,0.00001042836,0.00004381778,0.001222823,0.00004714484,0.000660648],"genre_scores_gemma":[0.9836122,0.001296353,0.008445431,0.00007447741,0.00001406177,0.00007328416,0.003813329,0.00003745209,0.002633455],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003147688,"threshold_uncertainty_score":0.006258726,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005008815507954218,"score_gpt":0.1763424493313336,"score_spread":0.1713336338233793,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}