{"id":"W2988288805","doi":"10.1107/s2056989019014622","title":"An iridium complex with an unsupported Ir—Zn bond: diiodido(η<sup>5</sup>-pentamethylcyclopentadienyl)bis(trimethylphosphane)iridiumzinc(<i>Ir</i>—<i>Zn</i>) benzene hemisolvate","year":2019,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Crystallographic Communications","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; University of Toronto","keywords":"Chemistry; Iridium; Adduct; Bimetallic strip; Lewis acids and bases; Benzene; Crystal structure; Medicinal chemistry; Crystallography; Stereochemistry; Metal; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001098553,0.0002317604,0.0003135345,0.0001518167,0.0001882221,0.0004337334,0.0009345511,0.0003560107,0.001337398],"category_scores_gemma":[0.0002077442,0.0002389503,0.00007219745,0.0004106365,0.0002816614,0.0002234684,0.0003735133,0.000362503,0.0002921768],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000866307,"about_ca_system_score_gemma":0.0003497807,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002001812,"about_ca_topic_score_gemma":0.002046978,"domain_scores_codex":[0.999862,0.00001507776,0.000006798981,0.00003916949,0.00004179464,0.00003514494],"domain_scores_gemma":[0.9999304,0.000006784187,0.00002254739,0.000007618012,0.000007647091,0.00002500879],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005623976,0.00006368089,0.0003332538,0.0001729665,0.00002349919,0.0001503117,0.00005781277,0.0005371307,0.9940553,0.001124505,0.0004954305,0.002423779],"study_design_scores_gemma":[0.0003016849,0.0003699964,0.001336206,0.000009143656,0.00004536263,0.0002664036,0.00003621694,0.001616945,0.9873211,0.00009660486,0.008587406,0.00001294402],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937159,0.0005853635,0.002235491,0.0001020148,0.00002441863,0.00002348592,0.0001816189,0.0001335251,0.002998186],"genre_scores_gemma":[0.9958164,0.0001913905,0.001774047,0.00002672734,0.000006073215,0.00001513944,0.0002154554,0.00002270801,0.00193219],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002001812,"threshold_uncertainty_score":0.006285548,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01652867381748709,"score_gpt":0.2547406002046834,"score_spread":0.2382119263871963,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}