{"id":"W2988439419","doi":"10.1039/c9py01181a","title":"Synthesis of PMMA-based block copolymers by consecutive irreversible and reversible addition–fragmentation chain transfer polymerizations","year":2019,"lang":"en","type":"article","venue":"Polymer Chemistry","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"Consejo Nacional de Ciencia y Tecnología; Agence Nationale de la Recherche","keywords":"Chain transfer; Copolymer; Xanthate; Polymer chemistry; Monomer; Chemistry; Dithiocarbamate; Polymerization; Vinyl acetate; Catalytic chain transfer; Radical polymerization; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002618261,0.0005580367,0.0003048277,0.0002912518,0.0001895901,0.0002070629,0.0002624764,0.0002930989,0.002062396],"category_scores_gemma":[0.0003445541,0.0002607758,0.0002661042,0.0002311652,0.0001847002,0.0004213668,0.0002726873,0.0008300889,0.0007202554],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003239827,"about_ca_system_score_gemma":0.0003417214,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003132376,"about_ca_topic_score_gemma":0.0005246611,"domain_scores_codex":[0.99981,0.0000150139,0.00001813284,0.00004483694,0.00005457022,0.00005741928],"domain_scores_gemma":[0.9998347,0.00003225411,0.00004223564,0.00002971294,0.00002470939,0.00003649931],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000288588,0.00001417725,0.00003044292,0.00003561436,0.000004140202,0.00003399373,0.00001360763,0.0001217917,0.9971859,0.0003100197,0.00002577455,0.002195655],"study_design_scores_gemma":[0.00001247366,0.0001113251,0.0004118232,0.00000334974,0.000006966765,0.00004378885,0.000002996445,0.0004507493,0.997313,0.00004537394,0.001594382,0.000003734062],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9562098,0.003445707,0.03087129,0.0001687502,0.0002042639,0.0004463266,0.0005663151,0.0004731358,0.007614348],"genre_scores_gemma":[0.966529,0.001513038,0.02477755,0.00005043915,0.00003172166,0.0002011156,0.0003103469,0.00006541021,0.00652137],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002062396,"threshold_uncertainty_score":0.006899476,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004040928862360702,"score_gpt":0.1937506296069094,"score_spread":0.1897097007445487,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}