{"id":"W2990262305","doi":"10.1021/jacs.9b11112","title":"Trivalent Titanocene Alkyls and Hydrides as Well-Defined, Highly Active, and Broad Scope Precatalysts for Dehydropolymerization of Amine-Boranes","year":2019,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Canada; University of Victoria","keywords":"Chemistry; Boranes; Dehydrogenation; Amine gas treating; Metathesis; Hydride; Metallocene; Catalysis; Reactivity (psychology); Transition metal; Organic chemistry; Borane; Polymer chemistry; Medicinal chemistry; Combinatorial chemistry; Metal; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007100734,0.0001915394,0.0001266682,0.0001346968,0.0001010162,0.0001786716,0.0002513667,0.0001539311,0.0007265526],"category_scores_gemma":[0.00009022273,0.0001421553,0.00009312142,0.00008094764,0.0001695121,0.0001641704,0.0001875559,0.0002975812,0.0002283137],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002296527,"about_ca_system_score_gemma":0.0001519656,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004887792,"about_ca_topic_score_gemma":0.001906885,"domain_scores_codex":[0.9999436,0.00000362164,0.000005165445,0.00001070601,0.00002145117,0.00001546404],"domain_scores_gemma":[0.9999648,0.000004136157,0.00001161685,0.000004884836,0.000006712353,0.000007923142],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000028407,0.000009268781,0.00007247786,0.00004912181,0.000002946069,0.00003783771,0.00002849874,0.00007058701,0.997613,0.000314019,0.00004605378,0.001727777],"study_design_scores_gemma":[0.000004279751,0.00005537457,0.0002516517,0.000001155402,0.000003129981,0.00004559986,0.000006308292,0.0001250082,0.9981217,0.00002051939,0.001363336,0.000002012563],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9905159,0.001559256,0.003439122,0.00009203751,0.00003327039,0.00003443907,0.0001808936,0.0002238739,0.003921104],"genre_scores_gemma":[0.9944819,0.0005621108,0.002611135,0.00001882886,0.000007200773,0.00001596934,0.0001462771,0.00003041305,0.002126113],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007265526,"threshold_uncertainty_score":0.002430558,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006290702758365433,"score_gpt":0.2464103704945213,"score_spread":0.2401196677361559,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}