{"id":"W2992057192","doi":"10.1021/acs.inorgchem.9b02765","title":"Structures, Phase Behavior, and Fluorescent Properties of 3-Phenyl-1-(pyridin-2-yl)-1 <i>H</i> -pyrazol-5-amine and Its ZnCl <sub>2</sub> Complex","year":2019,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University; University of New Brunswick; Wilfrid Laurier University","funders":"Canada Foundation for Innovation; Government of Ontario; Natural Sciences and Engineering Research Council of Canada; Wilfrid Laurier University","keywords":"Chemistry; Bathochromic shift; Crystallography; Orthorhombic crystal system; Ligand (biochemistry); Photoluminescence; Hydrogen bond; Melting point; Supercooling; Amine gas treating; Crystal structure; Fluorescence; Phase transition; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00006268164,0.0003301937,0.0003875371,0.00002746882,0.0000895237,0.00005079984,0.0001775201,0.0002642766,0.0006724686],"category_scores_gemma":[0.00004854447,0.0003131097,0.00007289031,0.0001087178,0.0001219219,0.00008201668,0.0001888799,0.0003132783,0.000009798948],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000594009,"about_ca_system_score_gemma":0.00005173103,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001525258,"about_ca_topic_score_gemma":0.000002227235,"domain_scores_codex":[0.9984254,0.00001168194,0.0004150863,0.0005286106,0.0003121165,0.0003071586],"domain_scores_gemma":[0.9990519,0.00001582502,0.0002107773,0.0004326932,0.0001176731,0.0001711301],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009186385,0.0001473161,0.0004842233,0.0009118005,0.0000416597,0.00001337408,0.0001062892,0.000001093776,0.9951732,0.000005955138,0.0001177059,0.002905555],"study_design_scores_gemma":[0.002036761,0.00004452543,0.0003086259,0.0001012759,0.00008254926,0.0001991694,0.0001249494,0.0002956311,0.9958323,0.00001619873,0.000609993,0.0003479693],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973052,0.001730823,0.000003314295,0.00004014382,0.00006643282,0.0001736013,0.00007002658,0.00007796341,0.0005324626],"genre_scores_gemma":[0.9991637,0.0002679657,0.00002701568,0.0000389504,0.0001132782,0.00001186808,0.00005808159,0.00005382242,0.0002652495],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002557585,"threshold_uncertainty_score":0.9999321,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01252083143481541,"score_gpt":0.2117229371987011,"score_spread":0.1992021057638857,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}