{"id":"W2992057192","doi":"10.1021/acs.inorgchem.9b02765","title":"Structures, Phase Behavior, and Fluorescent Properties of 3-Phenyl-1-(pyridin-2-yl)-1 <i>H</i> -pyrazol-5-amine and Its ZnCl <sub>2</sub> Complex","year":2019,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University; University of New Brunswick; Wilfrid Laurier University","funders":"Canada Foundation for Innovation; Government of Ontario; Natural Sciences and Engineering Research Council of Canada; Wilfrid Laurier University","keywords":"Chemistry; Bathochromic shift; Crystallography; Orthorhombic crystal system; Ligand (biochemistry); Photoluminescence; Hydrogen bond; Melting point; Supercooling; Amine gas treating; Crystal structure; Fluorescence; Phase transition; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006494209,0.0001612523,0.00008776841,0.0001614753,0.000125495,0.0001850718,0.0002927562,0.0001838598,0.000736623],"category_scores_gemma":[0.0002888814,0.00009324306,0.00005184764,0.0001641909,0.0001874981,0.0001362859,0.00007402081,0.0001770342,0.0001768965],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004290727,"about_ca_system_score_gemma":0.0001133322,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001764708,"about_ca_topic_score_gemma":0.0009749313,"domain_scores_codex":[0.9999331,0.000008702813,0.000003411023,0.00001977283,0.00002040263,0.00001458288],"domain_scores_gemma":[0.9998715,0.00003051838,0.00004848443,0.000006722681,0.00002803929,0.00001467694],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002012395,0.00002611917,0.0006866528,0.00005530763,0.00000528533,0.00004981773,0.00006452005,0.0007927311,0.9942661,0.0003730137,0.0001416261,0.003337464],"study_design_scores_gemma":[0.0000170672,0.0001022013,0.003287998,0.000003455802,0.000005637153,0.00009147223,0.00002484495,0.003453023,0.9914978,0.00005400317,0.001455576,0.000006914112],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972249,0.0005948058,0.001063667,0.00004952162,0.000003842134,0.000006877976,0.0002116548,0.00003874181,0.0008059453],"genre_scores_gemma":[0.9973544,0.000312076,0.0009894753,0.00002040298,0.000002532202,0.00001504502,0.0003680003,0.00001075365,0.0009273416],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001764708,"threshold_uncertainty_score":0.003508866,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01252083143481541,"score_gpt":0.2117229371987011,"score_spread":0.1992021057638857,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}