{"id":"W2994357604","doi":"10.1039/c9qm00710e","title":"Subtle substitution controls the rainbow chromatic behaviour of multi-stimuli responsive core-expanded pyrenes","year":2019,"lang":"en","type":"article","venue":"Materials Chemistry Frontiers","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); Calgary Laboratory Services; Saskatoon Medical Imaging; University of Calgary","funders":"National Research Council Canada; Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; Canada Foundation for Innovation; University of Saskatchewan","keywords":"Solvatochromism; Substitution (logic); Rainbow; Core (optical fiber); Materials science; Solid-state; Chromatic scale; Crystal (programming language); Photochemistry; Chemistry; Organic chemistry; Optics; Composite material; Molecule; Computer science; Physical chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008441624,0.0001957506,0.0000957654,0.00008799048,0.00009693379,0.000217235,0.0001885321,0.0001662069,0.001941396],"category_scores_gemma":[0.0001941017,0.000110059,0.00007561009,0.00008357857,0.0001891025,0.0003478381,0.000215294,0.0003343054,0.000237667],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001760973,"about_ca_system_score_gemma":0.0001131843,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002416709,"about_ca_topic_score_gemma":0.000708867,"domain_scores_codex":[0.9999455,0.000005338723,0.000003498393,0.00001476572,0.00001311424,0.00001780557],"domain_scores_gemma":[0.9999191,0.00002511595,0.00002065365,0.00001046343,0.00001026687,0.00001442984],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005794131,0.00001161354,0.00006167249,0.00001999198,0.000001545168,0.00002144197,0.00001499665,0.0001274285,0.9978715,0.0003346027,0.00002980368,0.001447414],"study_design_scores_gemma":[0.000007145044,0.00008393054,0.0005849783,0.000002574083,0.000002249543,0.00003092825,0.00001252319,0.001207549,0.9974598,0.00006088075,0.0005422481,0.000005214371],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971355,0.0001010061,0.00110073,0.00001939572,0.00000622028,0.000006815554,0.00003816828,0.00004575478,0.001546432],"genre_scores_gemma":[0.9985233,0.00009477911,0.0005843684,0.00001131298,0.000001528695,0.000006592471,0.00003188012,0.0000137644,0.0007325238],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001941396,"threshold_uncertainty_score":0.006494582,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01953669508317538,"score_gpt":0.2544206137343283,"score_spread":0.234883918651153,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}