{"id":"W2994678521","doi":"10.1002/9780470682531.pat0980","title":"Boron‐Based Frustrated <scp>L</scp> ewis Pairs in Hydrogenation Catalysis","year":2019,"lang":"en","type":"other","venue":"","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Frustrated Lewis pair; Boron; Catalysis; Asymmetric hydrogenation; Stereoselectivity; Chemistry; Combinatorial chemistry; Enantioselective synthesis; Lewis acids and bases; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000216725,0.000461309,0.0004119347,0.0003380009,0.0003471637,0.0006768361,0.0004617469,0.0003897413,0.008846653],"category_scores_gemma":[0.0001159619,0.0001478512,0.0001948408,0.0004207428,0.0003650131,0.0006600539,0.0008248797,0.0005235297,0.003999775],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004518427,"about_ca_system_score_gemma":0.0002187506,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004373915,"about_ca_topic_score_gemma":0.0008295722,"domain_scores_codex":[0.9998943,0.00002265495,0.000005978899,0.00001436536,0.00003343009,0.0000293938],"domain_scores_gemma":[0.9999772,0.000006604022,0.000003602398,0.000004127051,0.000004441272,0.000004064889],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004819513,0.0001441454,0.0003602636,0.005694795,0.00009030234,0.001013998,0.0004260399,0.009871547,0.3266919,0.3167052,0.03179756,0.3067223],"study_design_scores_gemma":[0.00008210621,0.0006456288,0.0005520368,0.0003572178,0.00005652923,0.001180393,0.0002176975,0.01167375,0.3634204,0.04590686,0.5757957,0.0001116883],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.2929807,0.1591561,0.05667583,0.002090561,0.001289644,0.0001855005,0.001023894,0.001628543,0.4849692],"genre_scores_gemma":[0.8193285,0.07532771,0.01939555,0.0008146989,0.0002859031,0.0001869607,0.0007519132,0.0002904964,0.08361825],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.008846653,"threshold_uncertainty_score":0.02959496,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008535943449431588,"score_gpt":0.2178817656275654,"score_spread":0.2093458221781338,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}