{"id":"W2994781549","doi":"10.1515/pac-2019-0214","title":"Unravelling mechanistic insights in the platinum-catalysed dihydroalkoxylation of allenes","year":2019,"lang":"en","type":"article","venue":"Pure and Applied Chemistry","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Alberta Land Institute, University of Alberta; Horizon 2020 Framework Programme; University of East Anglia; Biotechnology and Biological Sciences Research Council; Engineering and Physical Sciences Research Council; Euskal Herriko Unibertsitatea","keywords":"Chemistry; Platinum; Nucleophile; Enol; Allene; Cationic polymerization; Catalysis; Reactivity (psychology); Methanol; Catalytic cycle; Photochemistry; Computational chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007175542,0.0001392373,0.000187106,0.00001802488,0.0000417242,0.00001984493,0.0001604783,0.0001345819,0.0002065778],"category_scores_gemma":[0.00001329409,0.0001119513,0.0000391606,0.0001122724,0.00003986567,0.00003309328,0.00003911858,0.0002060514,0.00001387631],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002592632,"about_ca_system_score_gemma":0.0000302988,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001344694,"about_ca_topic_score_gemma":0.000004639962,"domain_scores_codex":[0.9991888,0.000002442172,0.000240114,0.0002407588,0.0001874439,0.0001404451],"domain_scores_gemma":[0.9993489,0.0001521273,0.0001232327,0.0003284075,0.00001627652,0.00003107771],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001589427,0.00004778876,0.0001437823,0.0002955538,0.00002093735,0.000001258003,0.0006572946,0.00009140168,0.9968435,0.001222819,0.00001352858,0.0006462706],"study_design_scores_gemma":[0.0004841996,0.000002380619,0.00006946284,0.00004928451,0.00003871062,0.00001328858,0.00182777,0.0008916938,0.9924071,0.003065534,0.0009948673,0.0001557049],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.918267,0.0001646492,0.00007619266,0.00003777369,0.00001178961,0.00007759516,0.000008436427,0.00002127157,0.0813353],"genre_scores_gemma":[0.9992028,0.00003194323,0.00004221297,0.00001460886,0.00007306159,0.00002457076,0.000130974,0.00001420528,0.0004656117],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08093581,"threshold_uncertainty_score":0.4565241,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008330356114810688,"score_gpt":0.2052865997958098,"score_spread":0.1969562436809991,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}