{"id":"W2995576806","doi":"10.1039/c9sc04879k","title":"Synthesis, characterization and C–H amination reactivity of nickel iminyl complexes","year":2019,"lang":"en","type":"article","venue":"Chemical Science","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Biological and Environmental Research; Alfred P. Sloan Foundation; Natural Sciences and Engineering Research Council of Canada; Basic Energy Sciences; National Institute of General Medical Sciences; Office of Science; Division of Chemistry; Camille and Henry Dreyfus Foundation; U.S. Department of Energy; Harvard University; National Institutes of Health; National Science Foundation","keywords":"Reactivity (psychology); Amination; Nickel; Characterization (materials science); Chemistry; Combinatorial chemistry; Stereochemistry; Polymer chemistry; Organic chemistry; Materials science; Nanotechnology; Catalysis; Medicine","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001642641,0.00006429057,0.0001190675,0.00003087292,0.00004458353,0.00002564314,0.0001607981,0.00004338945,0.000247886],"category_scores_gemma":[0.000315631,0.00005650024,0.00002380792,0.0001624947,0.0003080377,0.0002529967,0.0000595606,0.00005218404,0.00001527716],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004693048,"about_ca_system_score_gemma":0.0000332262,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001434648,"about_ca_topic_score_gemma":2.442133e-7,"domain_scores_codex":[0.9992775,0.000003145857,0.0001283984,0.0002347129,0.0002317958,0.0001244827],"domain_scores_gemma":[0.9994204,0.0001604273,0.0001001455,0.0002071678,0.00005638665,0.00005549065],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000003752195,0.00003855216,0.002791659,0.00003201923,0.000001650594,6.239924e-8,0.00003549168,6.389967e-8,0.9728125,0.0002931703,0.000003629284,0.02398741],"study_design_scores_gemma":[0.00004571836,0.000002212584,0.02599469,0.00003566649,0.000007299844,0.000004530913,0.00005233628,0.0003806135,0.9728267,0.00004553452,0.0005373787,0.00006732041],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910963,0.000007189486,0.00005672459,0.0000983893,0.00002728167,0.00003146417,0.00001178802,0.00001778894,0.008653061],"genre_scores_gemma":[0.9996367,0.00001232121,0.00008015741,0.000007637701,0.00002043688,0.000006222598,0.000009610979,0.000004031184,0.0002228844],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02392009,"threshold_uncertainty_score":0.2714178,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01193719032492787,"score_gpt":0.2363909501049208,"score_spread":0.2244537597799929,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}