{"id":"W2995576806","doi":"10.1039/c9sc04879k","title":"Synthesis, characterization and C–H amination reactivity of nickel iminyl complexes","year":2019,"lang":"en","type":"article","venue":"Chemical Science","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Biological and Environmental Research; Alfred P. Sloan Foundation; Natural Sciences and Engineering Research Council of Canada; Basic Energy Sciences; National Institute of General Medical Sciences; Office of Science; Division of Chemistry; Camille and Henry Dreyfus Foundation; U.S. Department of Energy; Harvard University; National Institutes of Health; National Science Foundation","keywords":"Reactivity (psychology); Amination; Nickel; Characterization (materials science); Chemistry; Combinatorial chemistry; Stereochemistry; Polymer chemistry; Organic chemistry; Materials science; Nanotechnology; Catalysis; Medicine","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001969453,0.0002432213,0.0001491063,0.0001481701,0.0002539031,0.0002405227,0.0003160344,0.0002077704,0.001125804],"category_scores_gemma":[0.0003070924,0.0001005597,0.00008525971,0.0001337784,0.0001600558,0.0001606038,0.0001601787,0.0002189559,0.0002908277],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004331077,"about_ca_system_score_gemma":0.0001261475,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001014829,"about_ca_topic_score_gemma":0.001595631,"domain_scores_codex":[0.9998437,0.00001786748,0.00001453681,0.00003364374,0.00005782722,0.000032387],"domain_scores_gemma":[0.9998815,0.00001725668,0.00002804497,0.00002416931,0.0000348829,0.00001412772],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001543967,0.00002281098,0.0002987708,0.00004202037,0.000005413569,0.00004430852,0.0000783983,0.0001186359,0.9968163,0.0003877551,0.0001391529,0.001891986],"study_design_scores_gemma":[0.000003951923,0.00007864784,0.0008090628,0.000002169696,0.000004178519,0.00005879748,0.00001678314,0.000481297,0.9967862,0.00002276179,0.001732443,0.000003704375],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9902484,0.0004899282,0.003106832,0.00005548615,0.00001045311,0.00004391234,0.0003157671,0.00005351681,0.005675538],"genre_scores_gemma":[0.9939803,0.0002362476,0.00178881,0.00001451171,0.000004298478,0.00002613443,0.0004929736,0.00002305309,0.003433823],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001125804,"threshold_uncertainty_score":0.003766239,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01193719032492787,"score_gpt":0.2363909501049208,"score_spread":0.2244537597799929,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}